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Synthesis and Polymerizability of Atom-Bridged Bicyclic Monomers
Department of Chemistry and Biochemistry, University of Arizona, 1306 E University Blvd, Tucson, AZ 85721, USA
Received: 11 September 2012; in revised form: 19 November 2012 / Accepted: 20 November 2012 / Published: 5 December 2012
Abstract: ¨The synthesis and polymerizability of atom-bridged bicyclic monomers was surveyed. The monomers included lactams, ureas, urethanes, lactones, carbonates, ethers, acetals, orthoesters, and amines. Despite widely-varying structures, they almost all polymerized to give polymers with monocyclic rings in the chain. The polymerizations are grouped by mechanism: uncoordinated anionic, coordinated anionic, and cationic.
Keywords: alicyclic ring-containing polymers; anti-Bredt monomers; atom-bridged bicyclic monomers; ring-opening polymerizations
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Cite This Article
MDPI and ACS Style
Hall, H.K. Synthesis and Polymerizability of Atom-Bridged Bicyclic Monomers. Polymers 2012, 4, 1674-1686.
Hall HK. Synthesis and Polymerizability of Atom-Bridged Bicyclic Monomers. Polymers. 2012; 4(4):1674-1686.
Hall, Henry K. 2012. "Synthesis and Polymerizability of Atom-Bridged Bicyclic Monomers." Polymers 4, no. 4: 1674-1686.