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Article

Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O

1
Department of Chemistry, Life Sciences and Environmental Sustainability, University of Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy
2
Consorzio Interuniversitario Reattività Chimica e Catalisi (C.I.R.C.C.), Via Celsio Ulpiani 27, 70126 Bari, Italy
*
Author to whom correspondence should be addressed.
Crystals 2018, 8(5), 215; https://doi.org/10.3390/cryst8050215
Submission received: 16 March 2018 / Revised: 7 May 2018 / Accepted: 13 May 2018 / Published: 15 May 2018
(This article belongs to the Special Issue Crystal Structures of Compounds Containing Ions Selenite)

Abstract

:
Single crystals of Na[VO(SeO3)(HSeO3)]·1,5H2O have been prepared by solvent slow evaporation from an equimolar aqueous mixture of sodium selenite and vanadyl sulfate. The overall arrangement consists of VO6 octahedra, [SeO3]2− and [HSeO3] anions forming a strong backbone with channel-like voids, while sodium cations participate in the framework, ensuring the overall charge balance. The crystal packing of the material features channels with a star-shaped section showing a mean aperture of 6.10 Å with the oxygen atoms of the V=O moieties pointing towards the interior of the cavities. Their dimensions are the narrowest reported until now in vanadium selenite compounds. Disordered sodium cations with occupancy factor of 0.5 are found in the star-shaped section cavities together with disordered water molecules, interacting with each other via hydrogen bonds.

Graphical Abstract

1. Introduction

Compounds containing selenite or hydrogen selenite anions are of great interest within the scientific community, from synthetic, structural and chemical points of view.
The bridging properties of selenites for connecting to transition metal cations allow magnetic exchange between paramagnetic centers in oligonuclear transition metal selenite complexes [1]. Recently, the weakly coordinative capability of the Se(IV) electron lone pair has been found to give rise to supramolecular interactions, as observed for the polyoxoselenitepalladate anions [Pd153-SeO3)103-O)10Na]9− in the solid state [2]. Regarding the chemistry of extended solids, the stereochemically active lone pair of electrons in Se(IV) may cause the inorganic selenites to crystallize into non-centrosymmetric structures exhibiting interesting physical properties such as nonlinear optical second harmonic generation (SHG) [3,4]. Moreover, it has been observed that some selenites show a highly robust 3D open framework structure, which is retained upon the removal of guests or coordinated small molecules. Selenite and hydrogen selenite anions allow the formation of solid-state structures characterized by the presence of open channels and/or cavities able to house the selenium electron pair [5]. The porous structures of selenite derivatives open the possibility of using such compounds for the synthesis of Metal-Organic Frameworks (MOFs) or Porous Coordination Polymers (PCPs). The formation of either open-framework or non-centrosymmetric materials has been the focus of intense research for many years, since the combination of both an open-framework and non-centrosymmetry within a single compound is especially attractive. Templated vanadium selenites are considered interesting systems owing to the presence of multiple asymmetric building units. This includes the possibility of using chiral organic amines, out-of-center octahedral distortions on vanadium cations, and stereoactive lone pairs on the Se(IV) centers [6,7,8,9].
Hydrothermal techniques have been applied to metal selenite systems in order to obtain different crystal phases [6,9]. These reaction conditions are especially attractive for exploratory work because they promote the growth of large single crystals and can be tuned to accommodate nearly any metal center [10]. Metal oxides have been widely used, owing to their structural diversity and technologically advantageous properties [11].
Pursuing our interest in the chemistry of selenite transition metal complexes to be used as precursor for the preparation of the corresponding metal selenides, we reacted sodium selenite with transition metal salts in water solution at room temperature. In the case of the reaction between vanadyl sulfate and sodium selenite in acidic conditions, we observed the formation of a microcrystalline powder. This was unambiguously identified as Na[VO(SeO3)(HSeO3)]·1,5H2O. Its crystal structure is here discussed and compared with selenite and hydrogen selenite vanadyl phases reported in the literature.

2. Materials and Methods

2.1. General Techniques

All manipulations were carried out at room temperature in the air; vanadyl sulfate (97% purity), sodium selenite (98% purity), and solvents (Analytical Grade) were purchased and used as received (Aldrich, St. Louis, MO, USA). FTIR spectra (4000–400 cm−1) were recorded on a Nicolet Nexus spectrophotometer equipped with a Smart Orbit HATR accessory (diamond).

2.2. X-ray Data Collection, Structure Solution, and Refinement

The intensity data of the compound were collected on a Bruker APEX II single crystal diffractometer [12,13] equipped with an area detector using a graphite monochromated Mo Kα radiation (λ = 0.71073 Å). Crystallographic and experimental details of the reported structure are summarized in Table 1. The structure was solved by direct methods and refined by full-matrix least-squares procedures (based on Fo2) using SHELXL-2014/7 (version 2014/7) [14,15], first with isotropic thermal parameters and then with anisotropic thermal parameters in the last cycles of refinement for all the non-hydrogen atoms. The hydrogen atom of the hydrogen selenite anion was introduced into the geometrically calculated position. The sodium cation was found disordered in two positions with occupancy factor of 0.69 and 0.40 respectively. The structure has been deposited in the Inorganic Crystal Structure Database (ICSD) with CSD number 434385.

2.3. Preparation of Na[VO(SeO3)(HSeO3)]·1,5H2O

A water solution (10 mL) of Na2SeO3 (0.706 g, 4.1 mmol) was prepared and acidified by adding an equimolar amount of a sulfuric acid solution (96%) [d = 1.84 g/mL]. A pale blue water solution (15 mL) containing VOSO4 (0.665 g, 4.1 mmol) was added dropwise to the first solution at room temperature. The clear blue solution was stirred for 20 min. Then the solvent was left to evaporate, and small amount of deep green crystals suitable for X-ray analysis were obtained. FTIR (Diamond crystal HATR): ν (SeO32−) = 693 cm−1, ν (VO2+) = 958 cm−1.

3. Results and Discussion

3.1. Chemistry and Crystal Growth

The exchange reaction between Na2SeO3 and VOSO4 salts in water solution and at room temperature led to the formation of a vanadyl selenite hydrogen selenite phase, whose crystalline structure was fully elucidated by means of X-ray diffraction analysis on suitable single crystals obtained by slow evaporation of the solvent. A relatively small number of vanadium selenite compounds with analogous arrangement are present in the literature, although their syntheses have been carried out in hydrothermal conditions. In the phase here reported, the overall charge balance of the extended [VO(SeO3)(HSeO3)] network is ensured by sodium cations. According to the study by Olshansky et al., the acidic pH environment is necessary for the attainment of similar phases, and this can be extended also to the present case [16]. The overall chemical reaction equation is reported in Scheme 1.

3.2. Crystal Structure Description

The asymmetric unit of Na[VO(SeO3)(HSeO3)]·1,5H2O consists of 11 non-hydrogen atoms, among them one vanadium and two crystallographically independent Se atoms, namely Se1 and Se2, as shown in Figure 1. A list of the most important bond distances and angles is reported in the caption of the figure. A sodium atom is also present, disordered in two positions (Na1 and Na2) with occupancy factor of 0.5.
The vanadium atom lies in a distorted octahedral environment with six oxygen atoms: the terminal V=O, two make V-O-Se2 linkages, and the remaining three form V-O-Se1 linkages. The short V=O distance of 1.596(5) Å and the V-O bond distances ranging from 1.982(4) to 2.209(5) Å are in agreement with the mean values observed in similar moieties reported in the Crystallographic Data Bank [17]. In particular, as reported in Figure 2, the distorted octahedron presents the shortest and the longest V-O distances in trans to one another, with the remaining four V-O bond lengths on the equatorial plane. Moreover, the vanadium atom is out of the mean plane defined by the equatorial bonded oxygen atoms of 0.297(5) Å.
The two Se atoms exhibit a trigonal pyramidal geometry with a stereoactive lone pair. The three oxygen atoms around Se1 are connected to the neighboring VO6 octahedra with bond angles of 120.4(2), 120.3(2) and 122.7(3)° (mean value 121.1(2)°). The selenium lone pair occupies the tetrahedral site. In the case of Se2; however, only two of the oxygen atoms form such linkages, while the third is protonated. The V-O-Se2 bond angles involving the non-protonated oxygen atom are 115.8(2) and 123.9(2)°. The presence of a longer Se2-O6 bond distance of 1.756(1) Å and the absence of interactions of this oxygen with the vanadium atom are coherent the presence of a terminal OH group.

3.3. Analysis of Molecular Packing

The overall framework structure of the compound is built up of VO6, SeO3, and HSeO3 units. All three oxygen atoms of SeO3 are shared by three neighboring vanadium-oxygen octahedra in such a manner as to form a ladder developing along the c-axis, consisting of edge-shared eight membered rings, each ring composed of two Se and two V atoms and four bridging oxygen atoms, as shown in Figure 3.
These ladders are connected to one another by HSeO3 groups along the a-axis to form a layer in the ac-plane as shown in Figure 4. This connectivity leads to the formation of a sixteen-membered bifurcated aperture with the dimensions 8.664 Å and 9.058 Å (vanadium to vanadium distance). The Se-O-H pendant moiety dandling above and below the aperture.

3.4. Crystal Packing of Disordered Na+ Cation in the Channels

The chain and layer motif observed in compound Na[VO(SeO3)(HSeO3)]·1,5H2O is similar to that in earlier reported vanadium selenite compounds organically templated with nitrogen containing cations and is considered to be a building unit in the vanadium selenite, whose progressive building up process, from the one-dimensional structure to two and three-dimensional complex structures has been demonstrated [6,9].
Viewing the crystal packing along the c-axis, as depicted in Figure 5, it is evident to observe the formation of channels with a star-shaped section with a mean aperture of 6.10 Å (O to O distance), with the oxygen atoms of the V=O moieties pointing towards the interior of the cavities.
Both the V and Se atoms are in the +4 oxidation state, so that the framework charge is −1, [(VO)(HSeO3)(SeO3)] balanced by metal cations. In fact, disordered sodium cations are found in the star-shaped section cavities (Figure 5) together with water molecules, interacting each other via hydrogen bonds.
As far as the 16-member star-shaped apertures are concerned, similar types of channels are also observed in reported vanadium selenite compounds organically templated with nitrogen-containing cations [7,8,9,16].
The mean dimension of the diameter of the cavities can vary depending on the size of the cationic moiety located into the channel and the presence of crystallization solvent molecules. Figure 6 shows the crystal packing of structures containing vanadium selenite hydrogen selenite compounds reported in the literature, in which channels developing along one of the crystallographic axes are present.
The dimensions of the mean diameter of the channels are reported in Table 2. All deposited structures present a dimension greater than the one observed in the case of Na[VO(SeO3)(HSeO3)]·1,5H2O. This is due to the greater hindrance of the nitrogen-containing organic cations—sometimes cocrystallized together with solvent molecules—with respect to the dimension of the sodium atom. Moreover, the nitrogen-containing cations inserted into the channels reported in the literature are involved in a strong network of hydrogen bonds with the oxygen atoms of the selenite or hydrogen selenite anions.
In the crystallographic data bank of inorganic compounds, the crystal structures of the K[VO(SeO3)(HSeO3)] [18] and of NH4[VO(SeO3)(HSeO3)] [19] are described. In those cases, the crystal structure and the morphology, shape and dimensions of the channels are very different from those of the presented phase. In fact, in both potassium and ammonium containing structures, very similar to one another, the overall crystal packing is composed of chains built up by VO5 square pyramids pointing up and down alternatingly with respect to the direction of the chains and SeO3 trigonal pyramid units. These chains are connected to one another by very strong hydrogen bonds. Moreover, each VO5 interacts with adjacent VO5 through the long V∙∙∙O interaction. In the crystal packing of [NH4][H(VO)(SeO3)2] and [K][H(VO)(SeO3)2], narrow channels with an average diameter of 4.35 Å are formed, and the potassium atom or NH4+ cations, with analogous steric hindrance, can insert. Both cations strongly interact with the oxygen atoms of the selenite and hydrogen selenite anions by hydrogen bonds.

4. Conclusions

Carrying out a reaction between vanadyl sulfate and sodium selenite with a water solvent at room temperature and under acidic conditions, a novel selenite hydrogen selenite phase was formed. The formula is Na[VO(SeO3)(HSeO3)]·1,5H2O, and its structure is composed of chain and layer crystallographic motifs, similar to those observed in previously reported vanadium selenite compounds organically templated with nitrogen-containing cations. The crystal packing of the material features channels with a star-shaped section with a mean aperture of 6.10 Å. The dimension of the cavities is, to our knowledge, the narrowest that has been reported until now for vanadium selenite compounds. Other selenite phases containing simple inorganic cations have been reported in the literature, such as with potassium or ammonium. In the present case, the overall crystal network is more similar to the one observed in reported organically templated vanadium selenite compounds than to the potassium- or ammonium-containing selenite structures. We suggest that the dimensions of the sodium cations, which are remarkably smaller than those of ammonium or potassium cations, makes it possible to keep the formation of main channels, as observed in reported vanadium selenite compounds, available to host disordered sodium cations together with disordered solvent molecules. This size effect can be exploited to obtain open framework compounds, where the structural presence of the cations does not prevent the accessibility of the cavities.

Author Contributions

S.C., G.P. and C.G. contributed equally to the research and writing of the present paper.

Acknowledgments

University of Parma is gratefully acknowledged for financial support.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Delferro, M.; Graiff, C.; Marchiò, L.; Elviri, L.; Mazzani, M.; Riccò, M.; Predieri, G. Synthesis, Structural characterization, and magnetic properties of the heteroleptic dinuclear nickel selenite complex [{Ni(TMEDA)SeO3}2]. Eur. J. Inorg. Chem. 2011, 3327–3333. [Google Scholar] [CrossRef]
  2. Delferro, M.; Graiff, C.; Elviri, L.; Predieri, G. Self-assembly of polyoxoselenitopalladate nanostars [Pd153-SeO3)103-O)10Na]9− and their supramolecular pairing in the solid state. Dalton Trans. 2010, 39, 4479–4481. [Google Scholar] [CrossRef] [PubMed]
  3. Ok, K.-M.; Halasyamani, P.S. Asymmetric cationic coordination environments in new oxide materials: Synthesis and characterization of Pb4Te6M10O41 (M = Nb5+ or Ta5+). Inorg. Chem. 2004, 43, 4248–4253. [Google Scholar] [CrossRef] [PubMed]
  4. Halasyamani, P.S.; Poeppelmier, K.R. Noncentrosymmetric Oxides. Chem. Mater. 1998, 10, 2753–2769. [Google Scholar] [CrossRef]
  5. Wontcheu, J.; Schleid, T. Tb3O2Cl[SeO3]2 and Tb5O4Cl3[SeO3]2: Oxide Chloride Oxoselenates(IV) of Trivalent terbium with “lone-pair” channel or layer structures. Z. Anorg. Allg. Chem. 2005, 631, 309–315. [Google Scholar] [CrossRef]
  6. Dai, Z.; Shi, A.; Li, G.; Chen, X.; Lu, X.; Xu, Y.; Feng, S. Hydrothermal syntheses and structures of two novel vanadium selenites, {[VO(OH)(H2O)](SeO3)}4∙2H2O and (H3NCH2CH2NH3)[(VO)(SeO3)2]. J. Solid State Chem. 2003, 172, 205–211. [Google Scholar] [CrossRef]
  7. Olshansky, J.H.; Tran, T.T.; Hernandez, K.J.; Zeller, M.; Shiv Halasyamani, P.; Schrier, J.; Norquist, A.J. Role of hydrogen-bonding in the formation of polar achiral and nonpolar chiral vanadium selenite frameworks. Inorg. Chem. 2012, 51, 11040–11048. [Google Scholar] [CrossRef] [PubMed]
  8. Pasha, I.; Choudhury, A.; Rao, C.N.R. Organically templated vanadyl selenites with layered structures. Inorg. Chem. 2003, 42, 409–415. [Google Scholar] [CrossRef] [PubMed]
  9. Dai, Z.; Li, G.; Shi, Z.; Liu, X.; Feng, S. Hydrothermal synthesis and structural characterization of a new layered vanadium selenite: (C4N2H12)0.5[(VO)2(H2O)2(SeO3)2(HSeO3)]. Inorg. Chem. Commun. 2005, 8, 890–893. [Google Scholar] [CrossRef]
  10. Rabenau, A. The role of hydrothermal synthesis in preparative chemistry. Angew. Chem. Int. Ed. Engl. 1985, 24, 1026–1040. [Google Scholar] [CrossRef]
  11. Rao, C.N.R.; Behera, J.N.; Dan, M. Organically-templated metal sulfates, selenites and selenates. Chem. Soc. Rev. 2006, 35, 375–387. [Google Scholar] [CrossRef] [PubMed]
  12. Bruker-Nonius. SAINT, Version 7.06a; Bruker AXS Inc.: Madison, WI, USA, 2004. [Google Scholar]
  13. Sheldrick, G.M. SADABS—Bruker Nonius Area Detector Scaling and Absorption Correction—V2016/2; Bruker AXS Inc.: Madison, WI, USA, 2016. [Google Scholar]
  14. Sheldrick, G.M. SHELX97, Version Release 97–2; University of Göttingen: Göttingen, Germany, 1998. [Google Scholar]
  15. Sheldrick, G.M. A short history of SHELX. Acta Cryst. 2008, 64, 112–122. [Google Scholar] [CrossRef] [PubMed]
  16. Olshansky, J.H.; Wiener, K.J.; Smith, M.D.; Nourmahnad, A.; Charles, M.J.; Zeller, M.; Schrier, J.; Norquist, A.J. Formation principles for vanadium selenites: The role of pH on product composition. Inorg. Chem. 2014, 53, 12027–12035. [Google Scholar] [CrossRef] [PubMed]
  17. Halasyamani, P.S.; O’Hare, D. A new three-dimensional vanadium selenite, (VO)2(SeO3)3, with isolated and edge-shared VO6 octahedra. Inorg. Chem. 1997, 36, 6409–6412. [Google Scholar] [CrossRef]
  18. Kim, Y.H.; Lee, K.-S.; Kwon, Y.-U.; Han, O.H. K(VO)(SeO3)2H: A new one-dimensional compound with strong hydrogen bonding. Inorg. Chem. 1996, 35, 7394–7398. [Google Scholar] [CrossRef] [PubMed]
  19. Emirdag-Eanes, M.; Ibers, J.A. Synthesis and characterization of two vanadium chalcogenides, [NH4][H(VO)(SeO3)2] and Cs4[(VOS2)2(µ-O)], prepared solvothermally. J. Alloys Compd. 2003, 361, 66–70. [Google Scholar] [CrossRef]
Scheme 1. Chemical reaction equation.
Scheme 1. Chemical reaction equation.
Crystals 08 00215 sch001
Figure 1. ORTEP view of the asymmetric unit of Na[VO(SeO3)(HSeO3)]·1,5H2O. Ellipsoids are depicted at their 30% probability level. List of the most important bond distances [Å] and angles [deg]: Se1-O1 1.712(4), Se1-O3 1.698(4), Se1-O2 1.695(4), Se2-O5 1.656(4), Se2-O4 1.687(4), Se2-O6 1.7560(7), V-O1 1.993(4), V-O4 1.990(5), V-O7 1.596(5); O3-Se1-O1 99.3(2), O2-Se1-O1 100.5(2), O2-Se1-O3 97.6(2), O5-Se2-O4 100.5(2), O5-Se2-O6 97.08(17), O4-Se2-O6 98.83(19), O4-V-O1 162.2(2), O7-V-O1 97.2(2), O7V-O4 100.5(2), Se1-O1-V 120.4(2), Se2-O4-V 123.9(3).
Figure 1. ORTEP view of the asymmetric unit of Na[VO(SeO3)(HSeO3)]·1,5H2O. Ellipsoids are depicted at their 30% probability level. List of the most important bond distances [Å] and angles [deg]: Se1-O1 1.712(4), Se1-O3 1.698(4), Se1-O2 1.695(4), Se2-O5 1.656(4), Se2-O4 1.687(4), Se2-O6 1.7560(7), V-O1 1.993(4), V-O4 1.990(5), V-O7 1.596(5); O3-Se1-O1 99.3(2), O2-Se1-O1 100.5(2), O2-Se1-O3 97.6(2), O5-Se2-O4 100.5(2), O5-Se2-O6 97.08(17), O4-Se2-O6 98.83(19), O4-V-O1 162.2(2), O7-V-O1 97.2(2), O7V-O4 100.5(2), Se1-O1-V 120.4(2), Se2-O4-V 123.9(3).
Crystals 08 00215 g001
Figure 2. ORTEP diagram of the distorted vanadium octahedron, bond distances are reported in Å. Ellipsoids are depicted at their 30% probability level. Symmetry codes for atoms: ‘ = 2 − x, 2 − y, 1 − z; ‘’ = 2.5 − x, −0.5 + y, 1.5 − z; ‘’’ = 2 − x, y, 1.5 − z.
Figure 2. ORTEP diagram of the distorted vanadium octahedron, bond distances are reported in Å. Ellipsoids are depicted at their 30% probability level. Symmetry codes for atoms: ‘ = 2 − x, 2 − y, 1 − z; ‘’ = 2.5 − x, −0.5 + y, 1.5 − z; ‘’’ = 2 − x, y, 1.5 − z.
Crystals 08 00215 g002
Figure 3. Partial framework structure of Na[VO(SeO3)(HSeO3)]·1,5H2O evidencing the formation of a ladder developing along the c-axis consisting of edge-shared eight membered rings.
Figure 3. Partial framework structure of Na[VO(SeO3)(HSeO3)]·1,5H2O evidencing the formation of a ladder developing along the c-axis consisting of edge-shared eight membered rings.
Crystals 08 00215 g003
Figure 4. Extension of the ladders in Na[VO(SeO3)(HSeO3)]·1,5H2O along the a-axis to form a layer in the ac-plane. Sodium atoms and water molecules have been omitted for clarity.
Figure 4. Extension of the ladders in Na[VO(SeO3)(HSeO3)]·1,5H2O along the a-axis to form a layer in the ac-plane. Sodium atoms and water molecules have been omitted for clarity.
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Figure 5. Crystal packing viewed along the c-axis, evidencing the formation of channels with a star-shaped section in which disordered Na+ cations (purple) and water molecules can insert.
Figure 5. Crystal packing viewed along the c-axis, evidencing the formation of channels with a star-shaped section in which disordered Na+ cations (purple) and water molecules can insert.
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Figure 6. Channels developing in the crystal packing of reported vanadium selenite compounds organically templated with nitrogen containing cations.
Figure 6. Channels developing in the crystal packing of reported vanadium selenite compounds organically templated with nitrogen containing cations.
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Table 1. Summary of crystallographic data for Na[VO(SeO3)(HSeO3)]·1,5H2O.
Table 1. Summary of crystallographic data for Na[VO(SeO3)(HSeO3)]·1,5H2O.
Na[VO(SeO3)(HSeO3)]·1,5H2O
FormulaH4NaO8,5Se2V
FW371.88
crystal systemMonoclinic
space groupC2/c
a, Å18.5779(16)
b, Å7.5662(7)
c, Å12.5844(11)
β, deg111.612(1)
V, Å31644.6(3)
Z8
T(K)298
Dcalcd, g cm−33.004
F(000)1352.0
µ, cm−110.125
rflns collected9710
rflns unique1697
rflns observed [I > 2σ(I)]1365 [Rint = 0.0618]
Parameters134
R indices [I > 2σ(I)]R1 = 0.0382; wR2 = 0.1001
R indices (all data)R1 = 0.0504; wR2 = 0.1064
R1 = Σ||Fo| − |Fc||/Σ|Fo|. wR2 = [Σ[w(Fo2Fc2)2]/Σ[w(Fo2)2]].
Table 2. Mean diameter [Å] of the cavities found in the literature compared with the one observed in Na[VO(SeO3)(HSeO3)]·1,5H2O.
Table 2. Mean diameter [Å] of the cavities found in the literature compared with the one observed in Na[VO(SeO3)(HSeO3)]·1,5H2O.
Na[VO(SeO3)(HSeO3)]·1,5H2O123456789
6.106.50 [9]7.83 [16]7.38 [16]7.89 [16]7.95 [16]7.83 [7]8.27 [7]7.57 [7]6.40 [7]

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Canossa, S.; Predieri, G.; Graiff, C. Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O. Crystals 2018, 8, 215. https://doi.org/10.3390/cryst8050215

AMA Style

Canossa S, Predieri G, Graiff C. Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O. Crystals. 2018; 8(5):215. https://doi.org/10.3390/cryst8050215

Chicago/Turabian Style

Canossa, Stefano, Giovanni Predieri, and Claudia Graiff. 2018. "Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O" Crystals 8, no. 5: 215. https://doi.org/10.3390/cryst8050215

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