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Crystals 2017, 7(6), 160; doi:10.3390/cryst7060160

Synthesis, Crystal Structure and Hirshfeld Topology Analysis of Polymeric Silver(I) Complex with s-Triazine-Type Ligand

1
Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 426 Ibrahimia, 21321 Alexandria, Egypt
2
Department of Chemistry, Rabigh College of Science and Art, King Abdulaziz University, P.O. Box 80200, Jeddah 21589, Saudi Arabia
3
Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
*
Authors to whom correspondence should be addressed.
Academic Editor: Philip Lightfoot
Received: 16 May 2017 / Revised: 25 May 2017 / Accepted: 31 May 2017 / Published: 2 June 2017
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Abstract

The synthesis, single crystal X-ray diffraction (SC-XRD) characterization and Hirshfeld topology analysis of molecular packing of the coordination polymer [Ag2L(H2O)2(ClO4)2]n, where L = 2,4,6-trimorpholino-1,3,5-triazine were discussed. The asymmetric unit comprises one Ag2L(H2O)2(ClO4)2 unit. The coordination geometries around the two silver atoms are different where Ag(1) is hexa-coordinated with one L, two bridged water, and two bridged perchlorate augmented with one strong Ag-O interaction from the morpholine O-atom of another ligand (L) unit. The coordination environment is more like to a distorted octahedral arrangement according to the criteria of continuous shape measurements. Ag(2) is coordinated to one L, one terminal water and one terminal perchlorate leading to a distorted trigonal planar arrangement around Ag(2). Hirshfeld analysis of molecular packing indicated that the most important intermolecular contacts affect the molecular packing of the studied complex are the H...H and the O...H interactions. Atoms in molecules (AIM) and natural bond orbital (NBO) analyses were used to describe the strength and nature of the Ag-O and Ag-N interactions. View Full-Text
Keywords: silver(I); topology; AIM; Hirshfeld; s-triazine silver(I); topology; AIM; Hirshfeld; s-triazine
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Soliman, S.M.; El-Faham, A. Synthesis, Crystal Structure and Hirshfeld Topology Analysis of Polymeric Silver(I) Complex with s-Triazine-Type Ligand. Crystals 2017, 7, 160.

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