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Crystals 2012, 2(1), 105-109; doi:10.3390/cryst2010105
Communication

The Molecular Structure of 1,2:5,6-Di-O-isopropylidene-3-O-toluenesulfonyl-α-D-glucofuranose

1,* , 2
 and 3
1 Institut für Radiopharmazie, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraße 400, D 01328 Dresden, Germany 2 Leibniz Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, D 18059 Rostock, Germany 3 Institut für Chemie, Anorganische Festkörperchemie, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany
* Author to whom correspondence should be addressed.
Received: 5 December 2011 / Revised: 16 February 2012 / Accepted: 20 February 2012 / Published: 29 February 2012
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Abstract

The crystal and molecular structure of 1,2:5,6-di-O-isopropylidene-3-O-toluenesulfonyl-α-D-glucofuranose is reported. This compound crystallizes from a petroleum ether/ethyl acetate mixture with the chiral orthorhombic space group P212121 with four molecules in the unit cell. The unit cell parameters are: a = 9.7945(7) Å, b = 10.1945(7) Å, c = 21.306(1) Å, and V = 2127.4(2) Å3. No classical hydrogen bonds were found. Bond lengths and angles of this tosylated glucofuranose derivative are typical.
Keywords: carbohydrates; glucose; tosylation carbohydrates; glucose; tosylation
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Mamat, C.; Peppel, T.; Köckerling, M. The Molecular Structure of 1,2:5,6-Di-O-isopropylidene-3-O-toluenesulfonyl-α-D-glucofuranose. Crystals 2012, 2, 105-109.

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