One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules
AbstractDuring the last decade, the combination of different metal- and bio-catalyzed organic reactions in aqueous media has permitted the flourishing of a variety of one-pot asymmetric multi-catalytic reactions devoted to the construction of enantiopure and high added-value chemicals under mild reaction conditions (usually room temperature) and in the presence of air. Herein, a comprehensive account of the state-of-the-art in the development of catalytic networks by combining metallic and biological catalysts in aqueous media (the natural environment of enzymes) is presented. Among others, the combination of metal-catalyzed isomerizations, cycloadditions, hydrations, olefin metathesis, oxidations, C-C cross-coupling and hydrogenation reactions, with several biocatalyzed transformations of organic groups (enzymatic reduction, epoxidation, halogenation or ester hydrolysis), are discussed. View Full-Text
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Ríos-Lombardía, N.; García-Álvarez, J.; González-Sabín, J. One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules. Catalysts 2018, 8, 75.
Ríos-Lombardía N, García-Álvarez J, González-Sabín J. One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules. Catalysts. 2018; 8(2):75.Chicago/Turabian Style
Ríos-Lombardía, Nicolás; García-Álvarez, Joaquín; González-Sabín, Javier. 2018. "One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules." Catalysts 8, no. 2: 75.
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