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Catalysts 2017, 7(9), 255; doi:10.3390/catal7090255

Continuous-Flow Monolithic Silica Microreactors with Arenesulphonic Acid Groups: Structure–Catalytic Activity Relationships

1
Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice, Poland
2
Department of Chemical Engineering and Process Design, Silesian University of Technology, Ks. M. Strzody 7, 44-100 Gliwice, Poland
*
Author to whom correspondence should be addressed.
Academic Editors: Tian-Yi Ma, Jian-Rong (Jeff) Li and Cláudia Gomes Silva
Received: 11 July 2017 / Revised: 28 August 2017 / Accepted: 28 August 2017 / Published: 30 August 2017
(This article belongs to the Special Issue Nanostructured Materials for Applications in Heterogeneous Catalysis)
View Full-Text   |   Download PDF [5302 KB, uploaded 30 August 2017]   |  

Abstract

The performance of monolithic silica microreactors activated with sulphonic acid groups and a packed bed reactor with Amberlyst 15 resin were compared in the esterification of acetic acid with n-butanol. The monolithic microreactors were made of single silica rods with complex pore architecture, differing in the size of mesopores, and in particular, flow-through macropores which significantly affected the flow characteristic of the continuous system. The highest ester productivity of 105.2 mol·molH+−1·h−1 was achieved in microreactor M1 with the largest porosity, characterized by a total pore volume of 4 cm3·g−1, mesopores with 20 nm diameter, and large flow-through macropores 30–50 μm in size. The strong impact of the permeability of the monoliths on a reaction kinetics was shown. View Full-Text
Keywords: silica monoliths; continuous-flow microreactors; acid centres; structure/catalytic activity relationships silica monoliths; continuous-flow microreactors; acid centres; structure/catalytic activity relationships
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Ciemięga, A.; Maresz, K.; Malinowski, J.J.; Mrowiec-Białoń, J. Continuous-Flow Monolithic Silica Microreactors with Arenesulphonic Acid Groups: Structure–Catalytic Activity Relationships. Catalysts 2017, 7, 255.

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