Next Article in Journal
The Reaction Mechanism of Acetaldehyde Ammoximation to Its Oxime in the TS-1/H2O2 System
Next Article in Special Issue
Au/TiO2-CeO2 Catalysts for Photocatalytic Water Splitting and VOCs Oxidation Reactions
Previous Article in Journal
Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C=C) Bond Catalyzed by Organocatalyst
Previous Article in Special Issue
Gold Catalysts on Y-Doped Ceria Supports for Complete Benzene Oxidation
Article Menu

Export Article

Open AccessFeature PaperReview
Catalysts 2016, 6(7), 107; doi:10.3390/catal6070107

Biomass Derived Chemicals: Furfural Oxidative Esterification to Methyl-2-furoate over Gold Catalysts

1
Department of Chemistry, University of Turin, NIS Centre of Excellence, Via P. Giuria 7, 10125 Torino, Italy
2
Department of Molecular Sciences and Nanosystems, Ca’ Foscari University Venice and INSTM Consortium RU Ve, Via Torino 155, 30170 Venezia Mestre, Italy
*
Author to whom correspondence should be addressed.
Academic Editors: Leonarda Liotta and Salvatore Scirè
Received: 16 March 2016 / Revised: 13 July 2016 / Accepted: 14 July 2016 / Published: 20 July 2016
(This article belongs to the Collection Gold Catalysts)
View Full-Text   |   Download PDF [4525 KB, uploaded 20 July 2016]   |  

Abstract

The use of heterogeneous catalysis to upgrade biomass wastes coming from lignocellulose into higher value-added chemicals is one of the most explored subjects in the prospective vision of bio-refinery. In this frame, a lot of interest has been driven towards biomass-derived building block molecules, such as furfural. Gold supported catalysts have been successfully proven to be highly active and selective in the furfural oxidative esterification to methyl-2-furoate under mild conditions by employing oxygen as benign oxidant. Particular attention has been given to the studies in which the reaction occurs even without base as co-catalyst, which would lead to a more green and economically advantageous process. The Au catalysts are also stable and quite easily recovered and represent a feasible and promising route to efficiently convert furfural to methyl-2-furoate to be scaled up at industrial level. View Full-Text
Keywords: gold catalyst; Au/ZrO2; Au/CeO2; Au/TiO2; Au clusters; Au perimeter sites; furfural; esterification; biomass gold catalyst; Au/ZrO2; Au/CeO2; Au/TiO2; Au clusters; Au perimeter sites; furfural; esterification; biomass
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Manzoli, M.; Menegazzo, F.; Signoretto, M.; Marchese, D. Biomass Derived Chemicals: Furfural Oxidative Esterification to Methyl-2-furoate over Gold Catalysts. Catalysts 2016, 6, 107.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Catalysts EISSN 2073-4344 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top