Pulsed Laser Deposition of Platinum Nanoparticles as a Catalyst for High-Performance PEM Fuel Cells
Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan
Department of Physics, National Central University, Taoyuan 320, Taiwan
Molecular Science and Technology Program, Taiwan International Graduate Program, Academia Sinica, Taipei 115, Taiwan
Department of Mechanical Engineering, National Central University, Taoyuan 320, Taiwan
Author to whom correspondence should be addressed.
Academic Editors: Vincenzo Baglio and David Sebastián
Received: 29 September 2016 / Revised: 7 November 2016 / Accepted: 17 November 2016 / Published: 22 November 2016
The catalyst layers for polymer-electrolyte-membrane (PEM) fuel cells were fabricated by deposition of platinum directly onto the gas diffusion layer using pulsed laser deposition (PLD). This technique reduced the number of steps required to synthesize the catalyst layers and the amount of Pt loading required. PEM fuel cells with various Pt loadings for the cathode were investigated. With a cathode Pt loading of 100
, the current density of a single cell reached 1205 mA·cm
at 0.6 V, which was close to that of a single cell using an E-TEK (trademark) Pt/C electrode with a cathode Pt loading of 400
. Furthermore, for a PEM fuel cell with both electrodes prepared by PLD and a total anode and cathode Pt loading of 117
, the overall Pt mass-specific power density at 0.6 V reached 7.43 kW·g
, which was five times that of a fuel cell with E-TEK Pt/C electrodes. The high mass-specific power density was due to that a very thin nanoporous Pt layer was deposited directly onto the gas diffusion layer, which made good contact with the Nafion membrane and thus resulted in a low-resistance membrane electrode assembly.
This is an open access article distributed under the Creative Commons Attribution License
which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
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MDPI and ACS Style
Qayyum, H.; Tseng, C.-J.; Huang, T.-W.; Chen, S.-Y. Pulsed Laser Deposition of Platinum Nanoparticles as a Catalyst for High-Performance PEM Fuel Cells. Catalysts 2016, 6, 180.
Qayyum H, Tseng C-J, Huang T-W, Chen S-Y. Pulsed Laser Deposition of Platinum Nanoparticles as a Catalyst for High-Performance PEM Fuel Cells. Catalysts. 2016; 6(11):180.
Qayyum, Hamza; Tseng, Chung-Jen; Huang, Ting-Wei; Chen, Szu-yuan. 2016. "Pulsed Laser Deposition of Platinum Nanoparticles as a Catalyst for High-Performance PEM Fuel Cells." Catalysts 6, no. 11: 180.
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