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Catalysts 2016, 6(10), 161; doi:10.3390/catal6100161

Palladium Nanoparticles Tethered in Amine-Functionalized Hypercrosslinked Organic Tubes as an Efficient Catalyst for Suzuki Coupling in Water

1
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2
Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032, India
*
Author to whom correspondence should be addressed.
Academic Editor: Ioannis D. Kostas
Received: 7 September 2016 / Revised: 14 October 2016 / Accepted: 14 October 2016 / Published: 20 October 2016
(This article belongs to the Special Issue Suzuki–Miyaura Cross-Coupling Reaction and Potential Applications)
View Full-Text   |   Download PDF [4197 KB, uploaded 20 October 2016]   |  

Abstract

It is highly desirable to design functionalized supports in heterogeneous catalysis regarding the stabilization of active sites. Pd immobilization in porous polymers and henceforth its application is a rapidly growing field. In virtue of its’ scalable synthesis and high stability in reaction conditions, amorphous polymers are considered an excellent scaffold for metal mediated catalysis, but the majority of them are found as either agglomerated particles or composed of rough spheres. Owing to several important applications of hollow organic tubes in diverse research areas, we aimed to utilize them as support for the immobilization of Pd nanoparticles. Pd immobilization in nanoporous polymer tubes shows high activity in Suzuki cross coupling reactions between aryl halides and sodium phenyl trihydroxyborate in water, which deserves environmental merit. View Full-Text
Keywords: porous organic tubes; heterogeneous catalysis; Suzuki coupling in water porous organic tubes; heterogeneous catalysis; Suzuki coupling in water
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Modak, A.; Sun, J.; Qiu, W.; Liu, X. Palladium Nanoparticles Tethered in Amine-Functionalized Hypercrosslinked Organic Tubes as an Efficient Catalyst for Suzuki Coupling in Water. Catalysts 2016, 6, 161.

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