Catalysts 2013, 3(3), 646-655; doi:10.3390/catal3030646
Article

Complete Toluene Oxidation on Pt/CeO2-ZrO2-ZnO Catalysts

email, , email and * email
Received: 25 May 2013; in revised form: 10 July 2013 / Accepted: 26 July 2013 / Published: 2 August 2013
(This article belongs to the Special Issue Catalytic Combustion)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: A 0.4 wt%Pt/Ce0.76Zr0.19Zn0.05O1.95 catalyst was prepared by the evaporative drying method. The catalytic toluene oxidation activity of the catalyst was investigated and the calcination temperature dependence on the toluene oxidation activity was characterized. It was confirmed that only CO2 and steam were produced by the complete oxidation of toluene, and no toluene-derived compounds were detected as by-products with a gas chromatography-mass spectrometer. Toluene was completely oxidized at 320 °C on the 0.4 wt%Pt/Ce0.76Zr0.19Zn0.05O1.95 catalyst calcined at 500 °C. The toluene oxidation activity slightly decreased with increasing the calcination temperature of the catalyst. However, significant deactivation was not recognized in the present 0.4 wt%Pt/Ce0.76Zr0.19Zn0.05O1.95 catalyst, and toluene was completely oxidized at 360 °C even after calcination at 1000 °C. From these results, it became obvious that the 0.4 wt%Pt/Ce0.76Zr0.19Zn0.05O1.95 catalyst has high thermal stability for toluene oxidation activity.
Keywords: volatile organic compounds; toluene; catalytic combustion; rare earth oxide; thermal stability
PDF Full-text Download PDF Full-Text [1015 KB, uploaded 2 August 2013 09:07 CEST]

Export to BibTeX |
EndNote


MDPI and ACS Style

Kim, M.Y.; Kamata, T.; Masui, T.; Imanaka, N. Complete Toluene Oxidation on Pt/CeO2-ZrO2-ZnO Catalysts. Catalysts 2013, 3, 646-655.

AMA Style

Kim MY, Kamata T, Masui T, Imanaka N. Complete Toluene Oxidation on Pt/CeO2-ZrO2-ZnO Catalysts. Catalysts. 2013; 3(3):646-655.

Chicago/Turabian Style

Kim, Min Y.; Kamata, Tomoya; Masui, Toshiyuki; Imanaka, Nobuhito. 2013. "Complete Toluene Oxidation on Pt/CeO2-ZrO2-ZnO Catalysts." Catalysts 3, no. 3: 646-655.

Catalysts EISSN 2073-4344 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert