Grain Refinement Efficiency in Commercial-Purity Aluminum Influenced by the Addition of Al-4Ti Master Alloys with Varying TiAl3 Particles
Abstract
:1. Introduction
2. Experimental
3. Results and Discussion
3.1. Microstructures and Morphologies
3.2. Refinement Performance of Al-4Ti Master Alloys
4. Conclusions
- (i)
- There were three different types of TiAl3 particles in Al-4Ti master alloys: petal-like structures, blocky structures, and flaky structures. The petal-like TiAl3 particles were only formed according to the growth mechanism of repeated twins when the aluminum melt augmented with K2TiF6 was casted into the graphite mold. Whether the K2TiF6 or sponge titanium was added into the aluminum melt which was cast into the sand mold, the flaky TiAl3 particles were generated. In addition, the blocky TiAl3 particles were found after the remaining three different processes.
- (ii)
- The grains in commercial-purity aluminum after grain refinement of Al-4Ti master alloys showed a hereditary effect on grain size. The larger the average grain sizes of the original TiAl3 particles were, the larger that of the refined commercial-purity aluminum was.
- (iii)
- With the increase in the hold time, the grain size of the commercial-purity aluminum refined by the Al-4Ti master alloy with petal-like TiAl3 particles increased, at first, and then decreased rapidly. The grain refinement efficiency of the Al-4Ti master alloy with blocky TiAl3 particles was the best and did not fade away with the change of the hold time. The Al-4Ti master alloy with flaky TiAl3 particles could instantly achieve a fine grain refinement under a hold time of five minutes; however, the fine refinement efficiency went down as the hold time increased.
- (iv)
- The grain refinement efficiency of Al-4Ti master alloys with the same morphology, size, and distribution of TiAl3 particles prepared through different processes was almost identical.
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Cast Material | Addition | Mold Materials | Alloy Designation |
---|---|---|---|
Pure aluminum | K2TiF6 | Graphite | I |
Copper | II | ||
Sand | III | ||
Sponge titanium | Graphite | IV | |
Copper | V | ||
Sand | VI |
Alloy | Morphology | Average Length, μm | Quantity, cm2 |
---|---|---|---|
I | Petal-like | 11 | 24,340 |
II | Blocky | 16 | 20,411 |
III | Needle-like | 90 | 7462 |
IV | Blocky | 13 | 23,750 |
V | Blocky | 22 | 17,900 |
VI | Needle-like | 106 | 6358 |
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Zhao, J.; He, J.; Tang, Q.; Wang, T.; Chen, J. Grain Refinement Efficiency in Commercial-Purity Aluminum Influenced by the Addition of Al-4Ti Master Alloys with Varying TiAl3 Particles. Materials 2016, 9, 869. https://doi.org/10.3390/ma9110869
Zhao J, He J, Tang Q, Wang T, Chen J. Grain Refinement Efficiency in Commercial-Purity Aluminum Influenced by the Addition of Al-4Ti Master Alloys with Varying TiAl3 Particles. Materials. 2016; 9(11):869. https://doi.org/10.3390/ma9110869
Chicago/Turabian StyleZhao, Jianhua, Jiansheng He, Qi Tang, Tao Wang, and Jing Chen. 2016. "Grain Refinement Efficiency in Commercial-Purity Aluminum Influenced by the Addition of Al-4Ti Master Alloys with Varying TiAl3 Particles" Materials 9, no. 11: 869. https://doi.org/10.3390/ma9110869