Materials 2013, 6(7), 2862-2872; doi:10.3390/ma6072862
Article

Role of Fluxes in Optimizing the Optical Properties of Sr0.95Si2O2N2:0.05Eu2+ Green-Emitting Phosphor

1,2email, 2,* email, 3email and 2email
Received: 10 April 2013; in revised form: 14 June 2013 / Accepted: 8 July 2013 / Published: 15 July 2013
(This article belongs to the Special Issue Luminescent Materials)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Chlorides of NH4Cl and SrCl2 and fluorides of AlF3 and SrF2 were added to raw materials acting as the flux for preparing the SrSi2O2N2:Eu2+ phosphor. The effects of the fluxes on the phase formation, particle morphology, particle size, and photoluminescence properties were investigated. The results revealed that particle size, particle morphology and photoluminescence intensity were largely dominated by the type of the flux material and its adding amount. The chloride-based flux was found to favor the formation of the SrSi2O2N2:Eu2+ phase. Among the chloride-based fluxes, the sample added with the SrCl2 flux presented the narrow particle distribution and cleaner surface, with enhanced emission intensity and an increased external quantum efficiency by 68% and 22%, respectively, compared with those of the sample without any flux adding.
Keywords: photoluminescence properties; oxynitride phosphor; flux; green emitting
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MDPI and ACS Style

Liu, L.; Xie, R.-J.; Zhang, C.; Hirosaki, N. Role of Fluxes in Optimizing the Optical Properties of Sr0.95Si2O2N2:0.05Eu2+ Green-Emitting Phosphor. Materials 2013, 6, 2862-2872.

AMA Style

Liu L, Xie R-J, Zhang C, Hirosaki N. Role of Fluxes in Optimizing the Optical Properties of Sr0.95Si2O2N2:0.05Eu2+ Green-Emitting Phosphor. Materials. 2013; 6(7):2862-2872.

Chicago/Turabian Style

Liu, Lihong; Xie, Rong-Jun; Zhang, Chenning; Hirosaki, Naoto. 2013. "Role of Fluxes in Optimizing the Optical Properties of Sr0.95Si2O2N2:0.05Eu2+ Green-Emitting Phosphor." Materials 6, no. 7: 2862-2872.

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