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Materials 2013, 6(7), 2662-2688; https://doi.org/10.3390/ma6072662

Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA

1
Faculty of Physics and Earth Science, University of Leipzig, Linnéstr. 5, D-04103 Leipzig, Germany
2
School of Chemical Engineering, University of Queensland, Brisbane QLD 4072, Australia
3
Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, 01069 Dresden, Germany
4
Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Daejeon 305-701, Korea
5
Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea
*
Author to whom correspondence should be addressed.
Received: 2 May 2013 / Revised: 12 June 2013 / Accepted: 17 June 2013 / Published: 4 July 2013
(This article belongs to the Special Issue Diffusion in Micropores and Mesopores 2013)
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Abstract

The presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsed field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in-depth study of molecular uptake and release on the individual particles of mesoporous zeolitic specimens, notably with samples of the narrow-pore structure types, CHA and LTA. The investigations are focused on determining the time constants and functional dependences of uptake and release. They include a systematic variation of the architecture of the mesopores and of the guest molecules under study as well as a comparison of transient uptake with blocked and un-blocked mesopores. In addition to accelerating intracrystalline mass transfer, transport enhancement by mesopores is found to be, possibly, also caused by a reduction of transport resistances on the particle surfaces. View Full-Text
Keywords: mesoporous zeolites; IR micro-imaging; diffusion; surface barriers; NaCaA; SAPO-34; paraffins; olefins mesoporous zeolites; IR micro-imaging; diffusion; surface barriers; NaCaA; SAPO-34; paraffins; olefins
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Bonilla, M.R.; Titze, T.; Schmidt, F.; Mehlhorn, D.; Chmelik, C.; Valiullin, R.; Bhatia, S.K.; Kaskel, S.; Ryoo, R.; Kärger, J. Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA. Materials 2013, 6, 2662-2688.

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