Materials 2013, 6(7), 2662-2688; doi:10.3390/ma6072662
Article

Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA

1 Faculty of Physics and Earth Science, University of Leipzig, Linnéstr. 5, D-04103 Leipzig, Germany 2 School of Chemical Engineering, University of Queensland, Brisbane QLD 4072, Australia 3 Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, 01069 Dresden, Germany 4 Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Daejeon 305-701, Korea 5 Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea
* Author to whom correspondence should be addressed.
Received: 2 May 2013; in revised form: 12 June 2013 / Accepted: 17 June 2013 / Published: 4 July 2013
(This article belongs to the Special Issue Diffusion in Micropores and Mesopores 2013)
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Abstract: The presence of mesopores in the interior of microporous particles may significantly improve their transport properties. Complementing previous macroscopic transient sorption experiments and pulsed field gradient NMR self-diffusion studies with such materials, the present study is dedicated to an in-depth study of molecular uptake and release on the individual particles of mesoporous zeolitic specimens, notably with samples of the narrow-pore structure types, CHA and LTA. The investigations are focused on determining the time constants and functional dependences of uptake and release. They include a systematic variation of the architecture of the mesopores and of the guest molecules under study as well as a comparison of transient uptake with blocked and un-blocked mesopores. In addition to accelerating intracrystalline mass transfer, transport enhancement by mesopores is found to be, possibly, also caused by a reduction of transport resistances on the particle surfaces.
Keywords: mesoporous zeolites; IR micro-imaging; diffusion; surface barriers; NaCaA; SAPO-34; paraffins; olefins

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MDPI and ACS Style

Bonilla, M.R.; Titze, T.; Schmidt, F.; Mehlhorn, D.; Chmelik, C.; Valiullin, R.; Bhatia, S.K.; Kaskel, S.; Ryoo, R.; Kärger, J. Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA. Materials 2013, 6, 2662-2688.

AMA Style

Bonilla MR, Titze T, Schmidt F, Mehlhorn D, Chmelik C, Valiullin R, Bhatia SK, Kaskel S, Ryoo R, Kärger J. Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA. Materials. 2013; 6(7):2662-2688.

Chicago/Turabian Style

Bonilla, Mauricio R.; Titze, Tobias; Schmidt, Franz; Mehlhorn, Dirk; Chmelik, Christian; Valiullin, Rustem; Bhatia, Suresh K.; Kaskel, Stefan; Ryoo, Ryong; Kärger, Jörg. 2013. "Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA." Materials 6, no. 7: 2662-2688.

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