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Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes
Key Laboratory of Petroleum and Gas Fine Chemicals, Educational Ministry of China, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
* Author to whom correspondence should be addressed.
Received: 20 May 2012; in revised form: 21 June 2012 / Accepted: 3 July 2012 / Published: 16 July 2012
Abstract: The polyaniline/single-walled carbon nanotubes (PANI/SWNTs) composites with a content of SWNTs varying from 8 wt% to 32 wt% were synthesized using a solid-state synthesis method. The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-visible (UV-vis) absorption spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical performances of the composites were investigated by galvanostatic charge–discharge and cycling stability measurements. The structure and properties of PANI/SWNTs were compared with those of PANI/multi-walled carbon nanotubes (PANI/MWNTs) prepared under the same polymerization conditions. The results from FTIR and UV-vis spectra showed that the composites with SWNTs displayed a higher oxidation and doping degree than pure PANI, which is similar to that of PANI/MWNTs. The morphological studies revealed that PANI/SWNTs did not display any rod-like and granular-like features, which appeared in PANI/MWNTs. The galvanostatic charge–discharge measurements indicated that the specific capacitance of PANI/SWNTs is not higher than that of PANI/MWNTs, but the PANI/SWNTs exhibited higher cycling stability and more stable electrochemical behavior in neutral and alkaline electrolytes than PANI/MWNTs.
Keywords: polyaniline; single-walled carbon nanotubes; composites solid-state polymerization
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MDPI and ACS Style
Abdiryim, T.; Ubul, A.; Jamal, R.; Rahman, A. Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes. Materials 2012, 5, 1219-1231.
Abdiryim T, Ubul A, Jamal R, Rahman A. Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes. Materials. 2012; 5(7):1219-1231.
Abdiryim, Tursun; Ubul, Aminam; Jamal, Ruxangul; Rahman, Adalet. 2012. "Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes." Materials 5, no. 7: 1219-1231.