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Fabrication of κ-Carrageenan Fibers by Wet Spinning: Spinning Parameters
Pennsylvania State University, University Park, PA 16802-1505, USA
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Received: 1 July 2011; in revised form: 26 September 2011 / Accepted: 28 September 2011 / Published: 11 October 2011
Abstract: This study demonstrates the fabrication of κ-carrageenan fibers by a wet-spinning method and discusses three important spinning parameters: coagulation bath composition, spinning rate and post-spinning mechanical drawing. The as-spun fiber diameter decreased with KCl and ethanol concentration in the coagulation bath. In general, the ultimate tensile stress and elongation at break both increased for KCl concentration from 0.1 to 0.5 M with and without ethanol, with no significant change above 0.5 M. Spinning rate affected the dope flow and thus the polymer orientation (apparent viscosity) and fiber morphology. At spinning rates between 0.25 mL/min and 0.33 mL/min, the fiber diameter reached a minimum and the fiber surface was smooth. Both an increase and decrease from this spinning rate range increased the fiber diameter and roughness of the fiber surface. Post-spinning drawing of the fiber resulted in even smaller fiber diameter.
Keywords: κ-carrageenan; fiber spinning; wet-spinning
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MDPI and ACS Style
Kong, L.; Ziegler, G.R. Fabrication of κ-Carrageenan Fibers by Wet Spinning: Spinning Parameters. Materials 2011, 4, 1805-1817.
Kong L, Ziegler GR. Fabrication of κ-Carrageenan Fibers by Wet Spinning: Spinning Parameters. Materials. 2011; 4(10):1805-1817.
Kong, Lingyan; Ziegler, Gregory R. 2011. "Fabrication of κ-Carrageenan Fibers by Wet Spinning: Spinning Parameters." Materials 4, no. 10: 1805-1817.