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Materials 2010, 3(4), 2447-2462; doi:10.3390/ma3042447
Article

New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity

1
, 1
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 and 1,*
Received: 31 January 2010; Accepted: 25 March 2010 / Published: 30 March 2010
(This article belongs to the Special Issue Organometallic Compounds)
Download PDF [452 KB, uploaded 30 March 2010]
Abstract: We present new element organic frameworks based on Sn, Sb and Bi atoms connected via organic linkers by element-carbon bonds. The open frameworks are characterized by specific surface areas (BET) of up to 445 m2 g-1 and a good stability under ambient conditions resulting from a highly hydrophobic inner surface. They show good performance as heterogeneous catalysts in the cyanosylilation of benzaldehyde as a test reaction. Due to their catalytic activity, this class of materials might be able to replace common homogeneous element-organic and often highly toxic catalysts especially in the food industry.
Keywords: element organic frameworks; EOF; heterogeneous catalysis element organic frameworks; EOF; heterogeneous catalysis
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Fritsch, J.; Rose, M.; Wollmann, P.; Böhlmann, W.; Kaskel, S. New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity. Materials 2010, 3, 2447-2462.

AMA Style

Fritsch J, Rose M, Wollmann P, Böhlmann W, Kaskel S. New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity. Materials. 2010; 3(4):2447-2462.

Chicago/Turabian Style

Fritsch, Julia; Rose, Marcus; Wollmann, Philipp; Böhlmann, Winfried; Kaskel, Stefan. 2010. "New Element Organic Frameworks Based on Sn, Sb, and Bi, with Permanent Porosity and High Catalytic Activity." Materials 3, no. 4: 2447-2462.


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