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Materials 2017, 10(8), 897; doi:10.3390/ma10080897

Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis

General and Physical Chemistry Department, Crimean Federal University, Simferopol 295007, Russia
A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russia
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia
Laboratory of Organic Electronics, Tomsk State University, Tomsk 634050, Russia
Institute of Applied Synthetic Chemistry, Vienna University of Technology, A-1060 Vienna, Austria
Author to whom correspondence should be addressed.
Received: 21 June 2017 / Revised: 8 July 2017 / Accepted: 20 July 2017 / Published: 3 August 2017
(This article belongs to the Section Structure Analysis and Characterization)
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New zinc and magnesium complexes of N-(2-carboxyphenyl)salicylidenimine) were synthesized and structurally characterized by elemental analysis, FT-IR, and X-ray single-crystal analysis. These complexes exhibit tuneable luminescence in the solid state from blue to green by varying by metal ion and composition. Moreover, the quantum yields range from 0.11 to 0.41, while lifetimes were determined to be in the nanosecond timescale. Thermal analysis shows that these complexes exhibit good thermal stability and can therefore well be used as electroluminescent materials. View Full-Text
Keywords: saliciylidenamide complex; Schiff base ligands; luminescence saliciylidenamide complex; Schiff base ligands; luminescence

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Gusev, A.; Braga, E.; Shul’gin, V.; Lyssenko, K.; Eremenko, I.; Samsonova, L.; Degtyarenko, K.; Kopylova, T.; Linert, W. Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis. Materials 2017, 10, 897.

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