Sensors 2007, 7(4), 438-447; doi:10.3390/s7040438
Article

Design of a Selective and Sensitive PVC-Membrane Potentiometric Sensor for Strontium Ion Based on 1,10-Diaza-5,6-benzo-4,7-dioxacyclohexadecane-2,9-dioneas a Neutral Ionophore

Mojtaba Shamsipur 1,* email, Sayed Yahya Kazemi 2  and Hashem Sharghi 3
1 Department of Chemistry, Razi University, Kermanshah, Iran 2 Department of Science, College of Agriculture, Mazandaran University, Sari, Iran 3 Department of Chemistry, Shiraz University, Shiraz, Iran
* Author to whom correspondence should be addressed.
Received: 6 February 2007 / Accepted: 16 March 2007 / Published: 12 April 2007
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Abstract: A novel PVC membrane sensor for the Sr2+ ion based on 1,10-diaza-5,6-benzo-4,7- dioxacyclohexadecane-2,9-dione has been prepared. The sensor possesses a Nernstian slope of 30.0 ± 0.6 mV decade-1 over a wide linear concentration range of 1.6 × 10-6-3.0 ×10-3 M with a detection limit of 6.3 ×10-7 M. It has a fast response time of less than 15 s and can be used for at least two months without any considerable divergence in potential. The potentiometric response is independent of the pH of test solution in the pH range 4.3-9.4. The proposed electrode shows good selectivities over a variety of alkali, alkaline earth, and transition metal ions.
Keywords: ion-selective electrode; Sr2+; PVC-membrane; macrocyclic diamide; potentiometry

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MDPI and ACS Style

Shamsipur, M.; Kazemi, S.Y.; Sharghi, H. Design of a Selective and Sensitive PVC-Membrane Potentiometric Sensor for Strontium Ion Based on 1,10-Diaza-5,6-benzo-4,7-dioxacyclohexadecane-2,9-dioneas a Neutral Ionophore. Sensors 2007, 7, 438-447.

AMA Style

Shamsipur M, Kazemi SY, Sharghi H. Design of a Selective and Sensitive PVC-Membrane Potentiometric Sensor for Strontium Ion Based on 1,10-Diaza-5,6-benzo-4,7-dioxacyclohexadecane-2,9-dioneas a Neutral Ionophore. Sensors. 2007; 7(4):438-447.

Chicago/Turabian Style

Shamsipur, Mojtaba; Kazemi, Sayed Y.; Sharghi, Hashem. 2007. "Design of a Selective and Sensitive PVC-Membrane Potentiometric Sensor for Strontium Ion Based on 1,10-Diaza-5,6-benzo-4,7-dioxacyclohexadecane-2,9-dioneas a Neutral Ionophore." Sensors 7, no. 4: 438-447.

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