A Novel Coated Graphite Rod Th(IV) Ion Selective Electrode Based On Thorium Oxinate Complex and Its Application

Abstract: Preparation, characterization, and application of a novel coated graphite rod thorium selective electrode based on thorium 8-hydroxyquinolate [thorium oxinate, Th(C9H6NO)4.2H2O] complex ionophore as a sensing material, dioctylphthalate (DOP) as a solvent mediator, and PVC as a matrix have been developed. The coated graphite rod electrode exhibits a linear Nernstian response over the concentration range 5x10^-6 - 1x10^-1 mol l^-1 of Th(IV) ions, with a calibration slope of 15.5 ± 0.5 mV/concentration decade and a detection limit of 1.6x10^-6 mol l^-1. It has a fast response time and can be used for a period of two months without any divergence in potentials. The proposed electrode reveals a good selectivity for Th(IV) cation over a varity of other cations and could be used in the pH range of (3 - 5). The sensor was successfully applied in the determination of thorium in real (monazite sand) sample. The average recovery obtained is ranging from 97.0 to 93.4% with standard deviation of 1.5% (n=8).