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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xml:lang="en" article-type="research-article">
<front>
<journal-meta>
<journal-id journal-id-type="nlm-ta">Sensors</journal-id>
<journal-title>Sensors</journal-title>
<issn pub-type="epub">1424-8220</issn>
<publisher>
<publisher-name>Molecular Diversity Preservation International (MDPI)</publisher-name></publisher></journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.3390/s100807561</article-id>
<article-id pub-id-type="publisher-id">sensors-10-07561</article-id>
<article-categories>
<subj-group>
<subject>Article</subject></subj-group></article-categories>
<title-group>
<article-title>Bayesian Model for Matching the Radiometric Measurements of Aerospace and Field Ocean Color Sensors</article-title></title-group>
<contrib-group>
<contrib contrib-type="author">
<name><surname>Salama</surname><given-names>Mhd. Suhyb</given-names></name><xref ref-type="corresp" rid="c1-sensors-10-07561">★</xref></contrib>
<contrib contrib-type="author">
<name><surname>Su</surname><given-names>Zhongbo</given-names></name></contrib>
<aff id="af1-sensors-10-07561">Faculty of Geo-Information Science and Earth Observation (ITC), University of Twente, Hengelosestraat 99, 7500 AA Enschede, The Netherlands; E-Mail: <email>b_su@itc.nl</email></aff></contrib-group>
<author-notes>
<corresp id="c1-sensors-10-07561">
<label>★</label> Author to whom correspondence should be addressed; E-Mail: <email>salama@itc.nl</email>; Tel.: +31 053 4874288; Fax: +31 053 4874336.</corresp></author-notes>
<pub-date pub-type="collection">
<year>2010</year></pub-date>
<pub-date pub-type="epub">
<day>11</day>
<month>8</month>
<year>2010</year></pub-date>
<volume>10</volume>
<issue>8</issue>
<fpage>7561</fpage>
<lpage>7575</lpage>
<history>
<date date-type="received">
<day>11</day>
<month>6</month>
<year>2010</year></date>
<date date-type="rev-recd">
<day>16</day>
<month>7</month>
<year>2010</year></date>
<date date-type="accepted">
<day>10</day>
<month>8</month>
<year>2010</year></date></history>
<permissions>
<copyright-statement>© 2010 by the authors; licensee MDPI, Basel, Switzerland.</copyright-statement>
<copyright-year>2010</copyright-year>
<license>
<p>This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).</p></license></permissions>
<abstract>
<p>A Bayesian model is developed to match aerospace ocean color observation to field measurements and derive the spatial variability of match-up sites. The performance of the model is tested against populations of synthesized spectra and full and reduced resolutions of MERIS data. The model derived the scale difference between synthesized satellite pixel and point measurements with R<sup>2</sup> &gt; 0.88 and relative error &lt; 21% in the spectral range from 400 nm to 695 nm. The sub-pixel variabilities of reduced resolution MERIS image are derived with less than 12% of relative errors in heterogeneous region. The method is generic and applicable to different sensors.</p></abstract>
<kwd-group>
<kwd>Bayesian</kwd>
<kwd>maximum entropy</kwd>
<kwd>match-up</kwd>
<kwd>ocean color</kwd>
<kwd>MERIS</kwd></kwd-group></article-meta></front>
<body>
<sec sec-type="intro">
<label>1.</label>
<title>Introduction</title>
<p>Consistent and accurate matching of aerospace observation data to field measurements are necessary calibration and validation steps towards creating reliable products of inherent optical properties (IOPs). The scientific procedure to match satellite observations to field measurements can generally be divided into three steps: <italic>i-</italic> measure remote sensing reflectance above the target in an area with homogenous optical properties; <italic>ii-</italic> re-sample the pixels of satellite data that surround the field site; <italic>iii-</italic> match the values obtained from step <italic>i</italic> to those computed from step <italic>ii</italic>. Accurate estimation of the sub-scale variability of the match-up site and its inclusion in the matching method is the most suitable approach to calibrate earth observation retrieval algorithms and validate their products.</p>
<p>Matching procedures for ocean color sensors were addressed by many researchers. For instance, Harding <italic>et al.</italic> [<xref ref-type="bibr" rid="b1-sensors-10-07561">1</xref>] selected field measurement sites in homogenous areas and Bailey and Werdell, [<xref ref-type="bibr" rid="b2-sensors-10-07561">2</xref>] averaged a number of spatially-homogeneous pixels surrounding the match-up site. Although, aggregating ocean color pixels was found to be suitable for open ocean [<xref ref-type="bibr" rid="b3-sensors-10-07561">3</xref>,<xref ref-type="bibr" rid="b4-sensors-10-07561">4</xref>], it lowers the percentage of usable match-up points considerably and should be avoided in coastal waters [<xref ref-type="bibr" rid="b5-sensors-10-07561">5</xref>]. Any direct matching in coastal turbid waters may result in large discrepancy [<xref ref-type="bibr" rid="b6-sensors-10-07561">6</xref>,<xref ref-type="bibr" rid="b7-sensors-10-07561">7</xref>]. Hyde <italic>et al.</italic> [<xref ref-type="bibr" rid="b8-sensors-10-07561">8</xref>] recognized that the mismatch between field measurement and SeaWiFS products of chlorophyll-a is partially due to difference in the sampling scales and therefore introduced a correction factor to overcome this scale mismatch.</p>
<p>In this paper we introduce a complete scheme to quantify the scale difference between a satellite pixel and a point (field) measurement. We used Bayesian inference method [<xref ref-type="bibr" rid="b9-sensors-10-07561">9</xref>] to estimate the probability distribution function (PDF) of the match-up pixel using the deviations between field and satellite measurements. We will discuss the methodology and performance of the model as applied to radiative transfer simulations [<xref ref-type="bibr" rid="b10-sensors-10-07561">10</xref>, IOCCG data set] and MERIS images at full and reduced resolutions acquired over the Dutch Bight.</p></sec>
<sec>
<label>2.</label>
<title>Method</title>
<sec>
<label>2.1.</label>
<title>Ocean color model</title>
<p>In this study we will use the model of Gordon <italic>et al.</italic> [<xref ref-type="bibr" rid="b11-sensors-10-07561">11</xref>] to relate the observed remote sensing reflectance that is leaving the water body <italic>Rs<sub>w</sub></italic>(<italic>λ</italic>) to the water biophysical properties:
<disp-formula id="FD1">
<label>(1)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mi>w</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>=</mml:mo>
<mml:mfrac>
<mml:mi>t</mml:mi>
<mml:mrow>
<mml:msubsup>
<mml:mi>n</mml:mi>
<mml:mi>w</mml:mi>
<mml:mn>2</mml:mn></mml:msubsup></mml:mrow></mml:mfrac>
<mml:munderover>
<mml:mo>∑</mml:mo>
<mml:mrow>
<mml:mi>i</mml:mi>
<mml:mo>=</mml:mo>
<mml:mn>1</mml:mn></mml:mrow>
<mml:mn>2</mml:mn></mml:munderover>
<mml:mrow>
<mml:msub>
<mml:mi>g</mml:mi>
<mml:mi>i</mml:mi></mml:msub></mml:mrow>
<mml:msup>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>b</mml:mi>
<mml:mi>b</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>b</mml:mi>
<mml:mi>b</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>+</mml:mo>
<mml:mi>a</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:mfrac></mml:mrow>
<mml:mo>)</mml:mo></mml:mrow>
<mml:mi>i</mml:mi></mml:msup></mml:mrow></mml:math></disp-formula>where <italic>g</italic><sub>1</sub>, <italic>g</italic><sub>2</sub> are subsurface expansion coefficients due to internal refraction, reflection and sun zenith; <italic>t</italic> and <italic>n<sub>w</sub></italic> are the sea air transmission and water index of refraction, respectively. Their values are taken to be: <italic>g</italic><sub>1</sub> = 0.0949, <italic>g</italic><sub>2</sub> = 0.0794, <italic>t</italic> = 0.95, <italic>n<sub>w</sub></italic> = 1.34. The quantities <italic>b<sub>b</sub></italic>(<italic>λ</italic>) and <italic>a</italic>(<italic>λ</italic>) are the bulk backscattering and absorption coefficients of the water column. Case II water is considered with five independently varying constituents, namely: water molecules, chlorophyll-a (Chl-a), detritus, dissolved organic matter and suspended particulate matter (SPM). The absorption <italic>a</italic>(<italic>λ</italic>) and backscattering <italic>b<sub>b</sub></italic>(<italic>λ</italic>) coefficients are parameterized as reported in Salama <italic>et al.</italic>[<xref ref-type="bibr" rid="b12-sensors-10-07561">12</xref>,<xref ref-type="bibr" rid="b13-sensors-10-07561">13</xref>] and summarized in <xref ref-type="app" rid="app1">Appendix 1</xref>. We will consider three main variables as derived from (1) using the method of Salama <italic>et al.</italic> [<xref ref-type="bibr" rid="b12-sensors-10-07561">12</xref>]. These variables are: (i) – the absorption coefficient of Chl-a at 440 nm, <italic>a<sub>phy</sub></italic>(440); (ii) – the combined absorptions of detritus and dissolved organic matter at 440 nm, <italic>a<sub>dg</sub></italic>(440); (iii) – the scattering coefficient of SPM at 550 nm, <italic>b<sub>spm</sub></italic>(550). The derived variables are called the set of IOPs and denoted in a vector notation <bold>iop</bold>.</p></sec>
<sec>
<label>2.2.</label>
<title>Bayesian inference</title>
<p>Our basic assumption is that each pixel in aerospace ocean color data represents the mean of an unknown theoretical probability distribution function (PDF) over a pixel area. In this respect, any field measured radiance is a sample drawn from this PDF [<xref ref-type="bibr" rid="b14-sensors-10-07561">14</xref>]. Our objective is to estimate the standard deviation of this PDF which represents the scale difference between pixel and point measurement. This standard deviation is also equal to the sub-scale variability of the satellite pixel. We will use the words (sub-scale variability) to represents the scale-difference and quantify the standard deviation as its measure.</p>
<p>The radiometric mismatch, between aerospace and field sensors, is attributed to the scale difference and is represented as an upper and lower bounds with a 1−<italic>α</italic> of confidence using the method of Bates and Watts [<xref ref-type="bibr" rid="b15-sensors-10-07561">15</xref>]:
<disp-formula id="FD2">
<label>(2)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo>±</mml:mo></mml:msub>
<mml:mo>=</mml:mo>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>±</mml:mo>
<mml:mi>σ</mml:mi>
<mml:mrow>
<mml:mo>‖</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac>
<mml:msup>
<mml:mi mathvariant="bold">R</mml:mi>
<mml:mrow>
<mml:mo>−</mml:mo>
<mml:mn>1</mml:mn></mml:mrow></mml:msup></mml:mrow>
<mml:mo>‖</mml:mo></mml:mrow>
<mml:mi>t</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>N</mml:mi>
<mml:mo>−</mml:mo>
<mml:mi>m</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>α</mml:mi>
<mml:mo>/</mml:mo>
<mml:mn>2</mml:mn>
<mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:math></disp-formula>where, <italic>Rs</italic><sub>±</sub> is the upper “+” and lower “−” bounds of <italic>Rs</italic>(<italic>λ</italic>); <italic>Rs</italic>(<italic>λ</italic>) is the observed radiometric quantity; <italic>σ</italic> is the standard deviation of the radiometric difference between field and aerospace measurements; <italic>t</italic>(<italic>N</italic> − <italic>m</italic>, <italic>α</italic>/2) is the upper quantile for a Student’s <italic>t</italic> distribution with <italic>N</italic> − <italic>m</italic> degrees of freedom. <italic>N</italic> is the number of bands and <italic>m</italic> is the number of unknowns. <bold>R</bold> is the upper triangle matrix of QR decomposition of the jacobian matrix. The derivative term in (2), can be approximated as being the gradient of (1) with respect to the derived IOPs and is computed for model-best-fit to the observation. This approximation is derived in <xref ref-type="app" rid="app1">Appendix 2</xref>.</p>
<p>The plausible range of the IOPs can be estimated from the upper and lower radiometric bounds by simply inverting (1) for the upper and lower radiometric bounds. A first estimate of the IOPs standard deviation is then derived form their plausible range using the method of Salama and Stein [<xref ref-type="bibr" rid="b9-sensors-10-07561">9</xref>]. This method is summarized in <xref ref-type="app" rid="app1">Appendix 3</xref>. Campbell [<xref ref-type="bibr" rid="b16-sensors-10-07561">16</xref>] showed that marine biophysical quantities are most likely log-normally distributed. We, therefore, use a log-normal distribution to generates random IOPs values within their plausible range using the estimated variance. We call these generated IOPs values a prior PDF of IOPs. The posterior probability of IOPs is then derived by maximizing the cross entropy H between prior and posterior information [<xref ref-type="bibr" rid="b17-sensors-10-07561">17</xref>,<xref ref-type="bibr" rid="b18-sensors-10-07561">18</xref>]:
<disp-formula id="FD3">
<label>(3)</label>
<mml:math display="block">
<mml:mrow>
<mml:mi mathvariant="normal">H</mml:mi>
<mml:mo>=</mml:mo>
<mml:munderover>
<mml:mo>∑</mml:mo>
<mml:mn>1</mml:mn>
<mml:mi>N</mml:mi></mml:munderover>
<mml:mrow>
<mml:mi mathvariant="normal">P</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mtext>iop</mml:mtext>
<mml:mo stretchy="false">|</mml:mo>
<mml:mi>ℓ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>⋅</mml:mo>
<mml:mtext>log</mml:mtext>
<mml:mfrac>
<mml:mrow>
<mml:mi mathvariant="normal">P</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mtext>iop</mml:mtext>
<mml:mo stretchy="false">|</mml:mo>
<mml:mi>ℓ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mi mathvariant="normal">P</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mtext>iop</mml:mtext>
<mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:mfrac></mml:mrow></mml:mrow></mml:math></disp-formula>where P(<bold>iop</bold>) is the prior probability and P(<bold>iop</bold>|<italic>ℓ</italic>) is the posterior probability of <bold>iop</bold> given the IOPs range <italic>ℓ.</italic> The empirical PDF of spectra is estimated from permutated values of the derived posterior PDF of IOPs. The importance of permutation is to simulate the ambiguity of remote sensing reflectance [<xref ref-type="bibr" rid="b19-sensors-10-07561">19</xref>] with respect to different sets of IOPs, <italic>i.e.</italic>, similar spectra corresponding to different sets of IOPs.</p></sec>
<sec>
<label>2.3.</label>
<title>Algorithm</title>
<p>The above-mentioned theoretical derivation of the Bayesian inference are summarize in the following algorithm:
<list list-type="order">
<list-item>
<p>use (2) to estimate the upper and lower bounds of spectra;</p></list-item>
<list-item>
<p>derive the IOPs ranges from these spectra by inverting (1);</p></list-item>
<list-item>
<p>use the method of section 3 to estimate the standard deviation of IOPs from their range;</p></list-item>
<list-item>
<p>generate the prior PDF of IOPs using log-normal distribution;</p></list-item>
<list-item>
<p>initiate the posterior using log-normal distribution;</p></list-item>
<list-item>
<p>maximize (3) to obtain an new estimate of the posterior;</p></list-item>
<list-item>
<p>update the posterior;</p></list-item>
<list-item>
<p>iterate between steps (5) and (6) till convergence;</p></list-item>
<list-item>
<p>permutate the resulting PDF of IOPs;</p></list-item>
<list-item>
<p>forward the sets of IOPs using (1) to obtain the empirical PDF of spectra.</p></list-item></list></p></sec></sec>
<sec sec-type="results">
<label>3.</label>
<title>Results</title>
<sec sec-type="methods">
<label>3.1.</label>
<title>Simulated data set</title>
<p>The proposed model was applied on [<xref ref-type="bibr" rid="b10-sensors-10-07561">10</xref>, IOCCG data set] of radiative transfer simulations at 30° sun zenith for synthesized sets of IOPs. The spectral arithmetic mean of this data set was computed to represent the observed aerospace spectrum. Spectra that corresponded to quantiles 0.05, 0.25, 0.5, 0.75, 0.9 and 0.95 were chosen to represent probable <italic>in-situ</italic> observations. The empirical distributions of the underlying population were derived and plotted in <xref ref-type="fig" rid="f1-sensors-10-07561">Figure 1</xref>.</p>
<p>Note that reflectance values are also log-normally distributed. <xref ref-type="fig" rid="f1-sensors-10-07561">Figure 1</xref> shows that the distribution resulting from the 0.5 quantile has the largest kurtosis and the smallest deviation from the theoretical mean. We performed modified Ansari-Bradley test [<xref ref-type="bibr" rid="b20-sensors-10-07561">20</xref>] at 5% significant level on the PDFs in <xref ref-type="fig" rid="f1-sensors-10-07561">Figure 1</xref>. This technique is a non-parametric two-samples test on dispersions of the theoretical and empirical PDFs. The results of the Ansari-Bradley test are shown in <xref ref-type="table" rid="t1-sensors-10-07561">Table 1</xref> as probabilities of the empirical PDF having the same dispersion as the theoretical PDF for radiometric and geo-biophysical quantities.</p>
<p>The Ansari-Bradley test shows that wavelength 495 nm is more probable to produce the sought variability regardless of the position of <italic>in-situ</italic> measurements in the theoretical PDF. Our model is more likely to derive the variability of all IOPs from the 0.95 quantile. The probability of deriving the variability of <italic>a<sub>dg</sub></italic>(440) and <italic>b<sub>spm</sub></italic>(550) is higher than deriving the variability of <italic>a<sub>phy</sub></italic>(440). <xref ref-type="fig" rid="f2-sensors-10-07561">Figure 2</xref> shows the relationships between the known and derived standard deviation with root-mean of squared errors (RMSE) and R<sup>2</sup> values derived from model-II regression [<xref ref-type="bibr" rid="b21-sensors-10-07561">21</xref>] of log-transformed radiometric data. The variability obtained from all quantiles have very close values to the theoretical variability with R<sup>2</sup> larger than 0.88. The RMSE values almost increase towards the median and start decreasing to reach a minimum value of 0.17 for 0.95 quantile. Close quantiles to the median (0.5) reproduce PDF with small dispersions. <xref ref-type="table" rid="t2-sensors-10-07561">Table 2</xref> shows the relative errors between known and derived (log) standard deviation. For all combinations of quantiles and wavelengths, the retrieved variabilities of reflectance were within 21% of known values. The root-mean of squared relative errors (RMS-RE) between known <italic>c</italic> and derived <italic>x</italic> values was computed for all wavelengths as shown in the last row of <xref ref-type="table" rid="t2-sensors-10-07561">Table 2</xref>:
<disp-formula id="FD4">
<label>(4)</label>
<mml:math display="block">
<mml:mrow>
<mml:mtext>RMS</mml:mtext>
<mml:mo>−</mml:mo>
<mml:mtext>RE</mml:mtext>
<mml:mo>=</mml:mo>
<mml:msqrt>
<mml:mrow>
<mml:mfrac>
<mml:mn>1</mml:mn>
<mml:mi>n</mml:mi></mml:mfrac>
<mml:munderover>
<mml:mo>∑</mml:mo>
<mml:mrow>
<mml:mi>i</mml:mi>
<mml:mo>=</mml:mo>
<mml:mn>1</mml:mn></mml:mrow>
<mml:mi>n</mml:mi></mml:munderover>
<mml:mrow>
<mml:msup>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mn>100</mml:mn>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>x</mml:mi>
<mml:mi>i</mml:mi></mml:msub>
<mml:mo>−</mml:mo>
<mml:mi>c</mml:mi></mml:mrow>
<mml:mi>c</mml:mi></mml:mfrac></mml:mrow>
<mml:mo>)</mml:mo></mml:mrow>
<mml:mn>2</mml:mn></mml:msup></mml:mrow></mml:mrow></mml:msqrt></mml:mrow></mml:math></disp-formula>where <italic>n</italic> in this case is the number of bands. The best results are obtained from field spectrum corresponding to the 0.95 quantile and RMS-RE values have the same trends as RMSE values shown in <xref ref-type="fig" rid="f2-sensors-10-07561">Figure 2</xref>, <italic>i.e.</italic>, increases towards the median from both sides.</p></sec>
<sec>
<label>3.2.</label>
<title>Model stability to atmospheric and random noise</title>
<p>The stability of the model to uncertainties in atmospheric correction and sensor noise was tested by perturbing the mean, <italic>i.e.</italic>, aerospace spectrum, with random normal fluctuations. The random perturbations were assumed to be wavelength dependent with zero mean and standard deviation calculated from the theoretical PDF. This implies that the residuals between the aerospace and field spectra are now due to three components, namely: errors originated from atmospheric correction, sensor noise and the spatial scale difference. The added fluctuations are within ±50% of the actual values as shown in appendix <xref ref-type="fig" rid="f3-sensors-10-07561">Figure 3</xref>. RMS-RE is computed between the log of known and derived estimates using (4) with <italic>n</italic> being the number of fluctuations. <xref ref-type="fig" rid="f4-sensors-10-07561">Figure 4</xref> shows that the RMS-RE values are less than 15% for derived variability values from the 0.05 and 0.95 quantiles. Derived values from 0.95 quantiles were more accurate than those derived using the 0.05 quantiles for wavelengths &gt; 500 nm.</p></sec>
<sec>
<label>3.3.</label>
<title>Ocean color radiometric products</title>
<p>We used full (FR) and reduced (RR) resolutions of MERIS images acquired over the North Sea [<xref ref-type="bibr" rid="b22-sensors-10-07561">22</xref>]. Atmospheric path correction was then performed using radiative transfer computation [<xref ref-type="bibr" rid="b23-sensors-10-07561">23</xref>] and the method of Salama and Shen [<xref ref-type="bibr" rid="b24-sensors-10-07561">24</xref>]. For this study, a region of the Dutch coastal waters was selected with relatively high optical variability. The sub-pixel variability of the reduced resolution image was derived for selected quantiles from the full resolution image. <xref ref-type="fig" rid="f5-sensors-10-07561">Figure 5</xref> shows the relative errors of the derived variability for band 6 of MERIS centered at 620 nm. The derived (log) standard deviation values were within 10% of relative errors in spatially variable areas and up to 40% in spatially homogenous waters. The mean and standard deviation of RMS-RE values of the images in <xref ref-type="fig" rid="f5-sensors-10-07561">Figure 5 (c–h)</xref> were between 7% and 8% and 7.3% and 7.5% respectively.</p></sec></sec>
<sec sec-type="discussion">
<label>4.</label>
<title>Discussion</title>
<p>Our method is formulated based on two steps. First we estimate the plausible range of IOPs. Second, we derive the posterior PDF of IOPs. In the first step we use the method of Bates and Watts [<xref ref-type="bibr" rid="b15-sensors-10-07561">15</xref>] to construct a bound-like around field and aerospace spectra. These spectra are inverted to derive the plausible range of IOPs. In the second step, we use the cross-entropy (3) as a utility function. The cross-entropy in (3) can be rewritten as: joint entropy minus the posterior’s entropy. Therefore maximizing (3) means maximizing the joint entropy between prior and posterior and minimizing the uncertainty about the posterior [<xref ref-type="bibr" rid="b18-sensors-10-07561">18</xref>], resulting in an optimum posterior and maximum joint entropy. <xref ref-type="disp-formula" rid="FD1">Equation (1)</xref> is then applied using the posterior PDF of IOPs to derive the empirical PDF of reflectance.</p>
<p>Validation with IOCCG data set shows that the root-mean of squared relative error is less than 15% for all possible field measurements. Moreover, derived values of variability are linearly related to the known values on a log scale with R<sup>2</sup> &gt; 0.88. Derived variability values from the green band, centered at ∼ 495 nm, are more probable and are invariant to the position of <italic>in-situ</italic> measurements in the theoretical PDF. The stability of the model is tested by imposing random fluctuations to the observed aerospace mean. The retrieved spatial variabilities from fluctuated data are within ±15% of the known values, with derived values from the 0.95 quantile being more accurate than those derived from the 0.05 quantile.</p>
<p>The proposed model is further tested with full and reduced resolution MERIS products covering part of the Dutch coastal waters. The highest errors in derived values of sub-pixels variability are in spatially homogenous areas. In these areas all quantile values are close to the mean and thus little information can be derived. This can also be observed in <xref ref-type="fig" rid="f2-sensors-10-07561">Figure 2</xref>. The results are slightly similar with respect to the different quantiles. However, derived variability from the 0.05 quantile was overestimated in turbid areas and provided good estimates in clear areas. The opposite was true for derived values using the 0.95 quantile, <italic>i.e.</italic>, better results were obtained in turbid waters. This is logic because in turbid waters it is difficult to find clear water pixels and in clear waters is difficult to find turbid water pixels. However, on the borders of the turbidity zone the method worked quite well. These areas exhibit the highest spatial variability at a given time. Our method derived accurate variability estimates in these edge-like areas. This behavior is apparent in <xref ref-type="fig" rid="f5-sensors-10-07561">Figure 5</xref>. Note the diagonal stripe from South-West to North-East separating the Dutch coastal waters and the high reflectance area in the North-West region of the image. This stripe indicates low error in derived variability.</p>
<p>Since atmospheric correction is a significant issue in water remote sensing [<xref ref-type="bibr" rid="b25-sensors-10-07561">25</xref>], imperfect atmospheric correction can lead to a significant error if not properly treated. A proper treatment is to combine our Bayesian model with the method of Salama and Stein [<xref ref-type="bibr" rid="b9-sensors-10-07561">9</xref>] to decompose the difference between satellite and field observations into error and scale components. The error component can be treated as in Salama and Stein [<xref ref-type="bibr" rid="b9-sensors-10-07561">9</xref>] and the scale component can be quantified using our Bayesian model.</p></sec>
<sec sec-type="conclusions">
<label>5.</label>
<title>Conclusions</title>
<p>In this paper we developed and applied a Bayesian approach to address the scale variability between point and aerospace measurements above water. The model used the differences between the field and aerospace observed spectra to derive prior information on the IOPs. We then applied Bayesian inference to derive the optimum posterior distribution of IOPs by maximizing the joint entropy of the prior-posterior. Our approach provided information about the sub-scale variability of match-up pixel on the IOPs and radiometric levels. We, further, showed that match-up sites for radiometric quantity could be inhomogeneous and preferably located on the edge of the turbidity zone. Information on the sub-scale variability of geo-biophysical processes will facilitate planning of calibration and validation of future sensors, resolving the critical scale of variability of an observed feature and improving the assimilation of EO products into model grid and field data. Although the approach was developed for radiometric quantities in a match-up pixel, it has the potential to be applied on bio-geophysical properties using prior knowledge on their plausible ranges. In addition, we believe that our methodology is general and applicable to land surface studies. The same principle applies: utilizing prior knowledge about geo-biophysical quantities to derive sub-scale variability of satellite pixel. However, the proposed model needs a more extensive validation with different data sets on land parameters.</p></sec></body>
<back>
<ack>
<p>The authors would like to thank the European Space Agency (ESA) for supplying MERIS data, Wim Timmermans from ITC, the Netherlands for providing technical assistance related to the Eagle 2006 data set, the Management Unit of the North Sea Mathematical Models (MUMM, Belgium) for maintaining the Oostende site. Anonymous reviewers are acknowledged for their comments.</p></ack>
<ref-list>
<title>References</title>
<ref id="b1-sensors-10-07561"><label>1.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Harding</surname><given-names>L</given-names><suffix>Jr</suffix></name><name><surname>Magnusona</surname><given-names>A</given-names></name><name><surname>Malloneea</surname><given-names>M</given-names></name></person-group><article-title>SeaWiFS retrievals of chlorophyll in Chesapeake Bay and the mid-Atlantic bight</article-title><source>Estuar. Coast. Shelf Sci</source><year>2005</year><volume>62</volume><fpage>75</fpage><lpage>94</lpage><pub-id pub-id-type="doi">10.1016/j.ecss.2004.08.011</pub-id></citation></ref>
<ref id="b2-sensors-10-07561"><label>2.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Bailey</surname><given-names>S</given-names></name><name><surname>Werdell</surname><given-names>J</given-names></name></person-group><article-title>A multi-sensor approach for the on-orbit validation of ocean color satellite data products</article-title><source>Remote Sens. Environ</source><year>2006</year><volume>102</volume><fpage>12</fpage><lpage>23</lpage><pub-id pub-id-type="doi">10.1016/j.rse.2006.01.015</pub-id></citation></ref>
<ref id="b3-sensors-10-07561"><label>3.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>McClain</surname><given-names>C</given-names></name><name><surname>Feldman</surname><given-names>G</given-names></name><name><surname>Hooker</surname><given-names>S</given-names></name></person-group><article-title>An overview of the SeaWiFS project and strategies for producing a climate research quality global ocean bio-optical time series</article-title><source>Deep-Sea Res. Pt. II-Top. St. Oce</source><year>2004</year><volume>51</volume><fpage>5</fpage><lpage>42</lpage><pub-id pub-id-type="doi">10.1016/j.dsr2.2003.11.001</pub-id></citation></ref>
<ref id="b4-sensors-10-07561"><label>4.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Garcia</surname><given-names>C</given-names></name><name><surname>Garcia</surname><given-names>V</given-names></name><name><surname>McClain</surname><given-names>C</given-names></name></person-group><article-title>Evaluation of SeaWiFS chlorophyll algorithms in the Southwestern Atlantic and Southern Oceans</article-title><source>Remote Sens. Environ</source><year>2005</year><volume>95</volume><fpage>125</fpage><lpage>137</lpage><pub-id pub-id-type="doi">10.1016/j.rse.2004.12.006</pub-id></citation></ref>
<ref id="b5-sensors-10-07561"><label>5.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Mélin</surname><given-names>F</given-names></name><name><surname>Berthon</surname><given-names>J</given-names></name><name><surname>Zibordi</surname><given-names>G</given-names></name></person-group><article-title>Assessment of apparent and inherent optical properties derived from SeaWiFS with field data</article-title><source>Remote Sens. Environ</source><year>2005</year><volume>97</volume><fpage>540</fpage><lpage>553</lpage><pub-id pub-id-type="doi">10.1016/j.rse.2005.06.002</pub-id></citation></ref>
<ref id="b6-sensors-10-07561"><label>6.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Darecki</surname><given-names>M</given-names></name><name><surname>Stramski</surname><given-names>D</given-names></name></person-group><article-title>An evaluation of MODIS and SeaWiFS bio-optical algorithms in the Baltic Sea</article-title><source>Remote Sens. Environ</source><year>2004</year><volume>89</volume><fpage>326</fpage><lpage>350</lpage><pub-id pub-id-type="doi">10.1016/j.rse.2003.10.012</pub-id></citation></ref>
<ref id="b7-sensors-10-07561"><label>7.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Chang</surname><given-names>G</given-names></name><name><surname>Gould</surname><given-names>R</given-names></name></person-group><article-title>Comparisons of optical properties of the coastal ocean derived from satellite ocean color and <italic>in situ</italic> measurements</article-title><source>Opt. Express</source><year>2006</year><volume>14</volume><fpage>10149</fpage><lpage>10163</lpage><pub-id pub-id-type="doi">10.1364/OE.14.010149</pub-id><pub-id pub-id-type="pmid">19529411</pub-id></citation></ref>
<ref id="b8-sensors-10-07561"><label>8.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Hyde</surname><given-names>K</given-names></name><name><surname>O’Reilly</surname><given-names>J</given-names></name><name><surname>Oviatt</surname><given-names>C</given-names></name></person-group><article-title>Validation of SeaWiFS chlorophyll-a in Massachusetts Bay</article-title><source>Cont. Shelf Res</source><year>2007</year><volume>27</volume><fpage>1677</fpage><lpage>1691</lpage><pub-id pub-id-type="doi">10.1016/j.csr.2007.02.002</pub-id></citation></ref>
<ref id="b9-sensors-10-07561"><label>9.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Salama</surname><given-names>MS</given-names></name><name><surname>Stein</surname><given-names>A</given-names></name></person-group><article-title>Error decomposition and estimation of inherent optical properties</article-title><source>Appl. Opt</source><year>2009</year><volume>48</volume><fpage>4926</fpage><lpage>4962</lpage><pub-id pub-id-type="doi">10.1364/AO.48.004926</pub-id><pub-id pub-id-type="pmid">19745856</pub-id></citation></ref>
<ref id="b10-sensors-10-07561"><label>10.</label><citation citation-type="other"><comment>IOCCG Remote Sensing of Inherent Optical Properties: Fundamentals, Tests of Algorithms, and Applications. Lee, Z.P., Ed.; IOCCG Report Number 5; International Ocean-Colour Coordinating Group: Dartmouth, Canada, 2006</comment></citation></ref>
<ref id="b11-sensors-10-07561"><label>11.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Gordon</surname><given-names>H</given-names></name><name><surname>Brown</surname><given-names>O</given-names></name><name><surname>Evans</surname><given-names>R</given-names></name><name><surname>Brown</surname><given-names>J</given-names></name><name><surname>Smith</surname><given-names>R</given-names></name><name><surname>Baker</surname><given-names>K</given-names></name><name><surname>Clark</surname><given-names>D</given-names></name></person-group><article-title>A semianalytical radiance model of ocean color</article-title><source>J Geophys Res</source><year>1988</year><volume>93</volume><fpage>10,909</fpage><lpage>10,924</lpage></citation></ref>
<ref id="b12-sensors-10-07561"><label>12.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Salama</surname><given-names>MS</given-names></name><name><surname>Dekker</surname><given-names>AG</given-names></name><name><surname>Su</surname><given-names>Z</given-names></name><name><surname>Mannaerts</surname><given-names>CM</given-names></name><name><surname>Verhoef</surname><given-names>W</given-names></name></person-group><article-title>Deriving inherent optical properties and associated inversion-uncertainties in the Dutch lakes</article-title><source>Hydrol. Earth Syst. Sci</source><year>2009</year><volume>13</volume><fpage>1113</fpage><lpage>1121</lpage><pub-id pub-id-type="doi">10.5194/hess-13-1113-2009</pub-id></citation></ref>
<ref id="b13-sensors-10-07561"><label>13.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Salama</surname><given-names>MS</given-names></name><name><surname>Shen</surname><given-names>F</given-names></name></person-group><article-title>Stochastic inversion of ocean color data using the cross-entropy method</article-title><source>Opt. Express</source><year>2010</year><volume>18</volume><fpage>479</fpage><lpage>499</lpage><pub-id pub-id-type="doi">10.1364/OE.18.000479</pub-id><pub-id pub-id-type="pmid">20173868</pub-id></citation></ref>
<ref id="b14-sensors-10-07561"><label>14.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Savelieva</surname><given-names>E</given-names></name><name><surname>Demyanov</surname><given-names>V</given-names></name><name><surname>Maignan</surname><given-names>M</given-names></name></person-group><article-title>Geostatistics: Spatial predictions and simulations</article-title><source>Adanced Mapping of Environmental Data: Geostatistics, Machine Learning and Bayesian Maximum Entropy</source><person-group person-group-type="editor"><name><surname>Kanevski</surname><given-names>M</given-names></name></person-group><publisher-name>Willey</publisher-name><publisher-loc>Hoboken, NJ, USA</publisher-loc><year>2008</year><fpage>47</fpage><lpage>94</lpage></citation></ref>
<ref id="b15-sensors-10-07561"><label>15.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Bates</surname><given-names>D</given-names></name><name><surname>Watts</surname><given-names>D</given-names></name></person-group><source>Nonlinear Regression Analysis and Its Applications</source><publisher-name>John Wiley Sons, Inc</publisher-name><publisher-loc>Hoboken, NJ, USA</publisher-loc><year>1988</year></citation></ref>
<ref id="b16-sensors-10-07561"><label>16.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Campbell</surname><given-names>J</given-names></name></person-group><article-title>The log-normal distribution as a model for bio-optical variability in the sea</article-title><source>J Geophys Res</source><year>1995</year><volume>100</volume><fpage>13,237</fpage><lpage>13,254</lpage></citation></ref>
<ref id="b17-sensors-10-07561"><label>17.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Rubinstein</surname><given-names>R</given-names></name><name><surname>Kroese</surname><given-names>D</given-names></name></person-group><source>The Cross-Entropy Method: A Unified Approach to Combinatorial Optimization, Monte-Carlo Simulation, and Machine Learning</source><publisher-name>Springer</publisher-name><publisher-loc>New York, NY, USA</publisher-loc><year>2004</year></citation></ref>
<ref id="b18-sensors-10-07561"><label>18.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Wu</surname><given-names>N</given-names></name></person-group><source>The Maximum Entropy Method (Springer Series in Information Sciences)</source><publisher-name>Springer</publisher-name><publisher-loc>Berlin, Germany</publisher-loc><year>1997</year><volume>32</volume></citation></ref>
<ref id="b19-sensors-10-07561"><label>19.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Sydor</surname><given-names>M</given-names></name><name><surname>Gould</surname><given-names>R</given-names></name><name><surname>Arnone</surname><given-names>R</given-names></name><name><surname>Haltrin</surname><given-names>V</given-names></name><name><surname>Goode</surname><given-names>W</given-names></name></person-group><article-title>Uniqueness in remote sensing of the inherent optical properties of ocean water</article-title><source>Appl. Opt</source><year>2004</year><volume>43</volume><fpage>2156</fpage><lpage>2162</lpage><pub-id pub-id-type="doi">10.1364/AO.43.002156</pub-id><pub-id pub-id-type="pmid">15074426</pub-id></citation></ref>
<ref id="b20-sensors-10-07561"><label>20.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Ansari</surname><given-names>A</given-names></name><name><surname>Bradley</surname><given-names>R</given-names></name></person-group><article-title>Rank-Sum tests for dispersions</article-title><source>Ann. Math. Statist</source><year>1960</year><volume>31</volume><fpage>1174</fpage><lpage>1189</lpage><pub-id pub-id-type="doi">10.1214/aoms/1177705688</pub-id></citation></ref>
<ref id="b21-sensors-10-07561"><label>21.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Laws</surname><given-names>E</given-names></name></person-group><source>Mathematical Methods for Oceanographers: An introduction</source><publisher-name>John Wiley Sons, Inc</publisher-name><publisher-loc>New York, NY, USA</publisher-loc><year>1997</year></citation></ref>
<ref id="b22-sensors-10-07561"><label>22.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Su</surname><given-names>Z</given-names></name><name><surname>Timmermans</surname><given-names>W</given-names></name><name><surname>van der Tol</surname><given-names>C</given-names></name><name><surname>Dost</surname><given-names>R</given-names></name><name><surname>Bianchi</surname><given-names>R</given-names></name><name><surname>Gomez</surname><given-names>JA</given-names></name><name><surname>House</surname><given-names>A</given-names></name><name><surname>Hajnsek</surname><given-names>I</given-names></name><name><surname>Menenti</surname><given-names>M</given-names></name><name><surname>Magliulo</surname><given-names>V</given-names></name><name><surname>Esposito</surname><given-names>M</given-names></name><name><surname>Haarbrink</surname><given-names>R</given-names></name><name><surname>Bosveld</surname><given-names>F</given-names></name><name><surname>Rothe</surname><given-names>R</given-names></name><name><surname>Baltink</surname><given-names>H</given-names></name><name><surname>Vekerdy</surname><given-names>Z</given-names></name><name><surname>Sobrino</surname><given-names>J</given-names></name><name><surname>Timmermans</surname><given-names>J</given-names></name><name><surname>van Laake</surname><given-names>P</given-names></name><name><surname>Salama</surname><given-names>MS</given-names></name><name><surname>van der Kwast</surname><given-names>H</given-names></name><name><surname>Claassen</surname><given-names>E</given-names></name><name><surname>Stolk</surname><given-names>A</given-names></name><name><surname>Jia</surname><given-names>L</given-names></name><name><surname>Moors</surname><given-names>E</given-names></name><name><surname>O</surname><given-names>H</given-names></name><name><surname>Gillespie</surname><given-names>A</given-names></name></person-group><article-title>EAGLE 2006—Multi-purpose, multi-angle and multi-sensor <italic>in-situ</italic> and airborne campaigns over grassland and forest</article-title><source>Hydrol. Earth Syst. Sci</source><year>2009</year><volume>13</volume><fpage>833</fpage><lpage>845</lpage><pub-id pub-id-type="doi">10.5194/hess-13-833-2009</pub-id></citation></ref>
<ref id="b23-sensors-10-07561"><label>23.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Vermote</surname><given-names>E</given-names></name><name><surname>Tanre</surname><given-names>D</given-names></name><name><surname>Deuze</surname><given-names>J</given-names></name><name><surname>Herman</surname><given-names>M</given-names></name><name><surname>Morcrette</surname><given-names>J</given-names></name></person-group><article-title>Second simulation of the satellite signal in the solar spectrum, 6S: An overview</article-title><source>IEEE Trans. Geosci. Remote Sens</source><year>1997</year><volume>35</volume><fpage>675</fpage><lpage>686</lpage><pub-id pub-id-type="doi">10.1109/36.581987</pub-id></citation></ref>
<ref id="b24-sensors-10-07561"><label>24.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Salama</surname><given-names>MS</given-names></name><name><surname>Shen</surname><given-names>F</given-names></name></person-group><article-title>Simultaneous atmospheric correction and quantification of suspended particulate matters from orbital and geostationary earth observation sensors</article-title><source>Estuar. Coast. Shelf Sci</source><year>2010</year><volume>86</volume><fpage>499</fpage><lpage>511</lpage><pub-id pub-id-type="doi">10.1016/j.ecss.2009.10.001</pub-id></citation></ref>
<ref id="b25-sensors-10-07561"><label>25.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Salama</surname><given-names>S</given-names></name><name><surname>Monbaliu</surname><given-names>J</given-names></name><name><surname>Coppin</surname><given-names>P</given-names></name></person-group><article-title>Atmospheric correction of advanced very high resolution radiometer imagery</article-title><source>Int. J. Remote Sens</source><year>2004</year><volume>25</volume><fpage>1349</fpage><lpage>1355</lpage><pub-id pub-id-type="doi">10.1080/01431160310001592283</pub-id></citation></ref>
<ref id="b26-sensors-10-07561"><label>26.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Pope</surname><given-names>R</given-names></name><name><surname>Fry</surname><given-names>E</given-names></name></person-group><article-title>Absorption spectrum (380–700nm) of pure water: II, Integrating cavity measurements</article-title><source>Appl. Opt</source><year>1997</year><volume>36</volume><fpage>8710</fpage><lpage>8723</lpage><pub-id pub-id-type="doi">10.1364/AO.36.008710</pub-id><pub-id pub-id-type="pmid">18264420</pub-id></citation></ref>
<ref id="b27-sensors-10-07561"><label>27.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Mobley</surname><given-names>C</given-names></name></person-group><source>Light and Water Radiative Transfer in Natural Waters</source><publisher-name>Academic Press</publisher-name><publisher-loc>London, UK</publisher-loc><year>1994</year></citation></ref>
<ref id="b28-sensors-10-07561"><label>28.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Lee</surname><given-names>Z</given-names></name><name><surname>Carder</surname><given-names>K</given-names></name><name><surname>Mobley</surname><given-names>C</given-names></name><name><surname>Steward</surname><given-names>R</given-names></name><name><surname>Patch</surname><given-names>J</given-names></name></person-group><article-title>Hyperspectral remote sensing for shallow waters: 2. Deriving bottom depths and water properties by optimization</article-title><source>Appl. Opt</source><year>1999</year><volume>38</volume><fpage>3831</fpage><lpage>3843</lpage><pub-id pub-id-type="doi">10.1364/AO.38.003831</pub-id><pub-id pub-id-type="pmid">18319990</pub-id></citation></ref>
<ref id="b29-sensors-10-07561"><label>29.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Maritorena</surname><given-names>S</given-names></name><name><surname>Siegel</surname><given-names>D</given-names></name><name><surname>Peterson</surname><given-names>A</given-names></name></person-group><article-title>Optimization of a semianalytical ocean color model for global-scale applications</article-title><source>Appl. Opt</source><year>2002</year><volume>41</volume><fpage>2705</fpage><lpage>2714</lpage><pub-id pub-id-type="doi">10.1364/AO.41.002705</pub-id><pub-id pub-id-type="pmid">12027157</pub-id></citation></ref>
<ref id="b30-sensors-10-07561"><label>30.</label><citation citation-type="journal"><person-group person-group-type="author"><name><surname>Bricaud</surname><given-names>A</given-names></name><name><surname>Morel</surname><given-names>A</given-names></name><name><surname>Prieur</surname><given-names>L</given-names></name></person-group><article-title>Absorption by dissolved organic-matter of the sea (yellow substance) in the UV and visible domains</article-title><source>Limnol. Oceanog</source><year>1981</year><volume>26</volume><fpage>43</fpage><lpage>53</lpage><pub-id pub-id-type="doi">10.4319/lo.1981.26.1.0043</pub-id></citation></ref>
<ref id="b31-sensors-10-07561"><label>31.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Kopelevich</surname><given-names>O</given-names></name></person-group><article-title>Small-parameter model of optical properties of sea waters</article-title><source>Ocean Optics</source><person-group person-group-type="editor"><name><surname>Monin</surname><given-names>A</given-names></name></person-group><publisher-name>Nauka</publisher-name><publisher-loc>Moscow, Russia</publisher-loc><year>1983</year><volume>1</volume><fpage>208</fpage><lpage>234</lpage></citation></ref>
<ref id="b32-sensors-10-07561"><label>32.</label><citation citation-type="book"><person-group person-group-type="author"><name><surname>Petzold</surname><given-names>T</given-names></name></person-group><article-title>Volume scattering functions for selected ocean waters</article-title><source>Light in the Sea</source><person-group person-group-type="editor"><name><surname>Tyler</surname><given-names>J</given-names></name></person-group><publisher-name>Dowden, Hutchinson and Ross</publisher-name><publisher-loc>Stroudsburg, PA, USA</publisher-loc><year>1977</year><volume>12</volume><fpage>150</fpage><lpage>174</lpage></citation></ref></ref-list>
<app-group>
<app id="app1">
<title>Appendix</title>
<sec>
<label>1.</label>
<title>Parametrization of IOPs</title>
<p>The absorption and scattering coefficients of water molecules, <italic>a<sub>w</sub></italic> and <italic>b<sub>w</sub></italic>, were assumed constants and obtained from [<xref ref-type="bibr" rid="b26-sensors-10-07561">26</xref>,<xref ref-type="bibr" rid="b27-sensors-10-07561">27</xref>], respectively. The total absorption of phytoplankton pigments <italic>a<sub>phy</sub></italic> is approximated as [<xref ref-type="bibr" rid="b28-sensors-10-07561">28</xref>]:
<disp-formula id="FD5">
<label>(5)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">phy</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>=</mml:mo>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mn>0</mml:mn></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">phy</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mn>0.44</mml:mn>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>+</mml:mo>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mn>1</mml:mn></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">phy</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mn>0.44</mml:mn>
<mml:mo stretchy="false">)</mml:mo>
<mml:mi> </mml:mi>
<mml:mtext>ln</mml:mtext>
<mml:mi> </mml:mi>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">phy</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mn>0.44</mml:mn>
<mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:math></disp-formula>where <italic>a</italic><sub>0</sub>(λ) and <italic>a</italic><sub>1</sub>(λ) are empirical coefficients. The absorption effects of detritus and dissolved organic matter are combined due to the similar spectral signature [<xref ref-type="bibr" rid="b29-sensors-10-07561">29</xref>] and approximated using the model [<xref ref-type="bibr" rid="b30-sensors-10-07561">30</xref>]:
<disp-formula id="FD6">
<label>(6)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">dg</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>=</mml:mo>
<mml:msub>
<mml:mi>a</mml:mi>
<mml:mi mathvariant="italic">dg</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mn>440</mml:mn>
<mml:mo stretchy="false">)</mml:mo>
<mml:mi> </mml:mi>
<mml:mtext>exp</mml:mtext>
<mml:mo stretchy="false">[</mml:mo>
<mml:mo>−</mml:mo>
<mml:mi>s</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo>−</mml:mo>
<mml:mn>440</mml:mn>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo stretchy="false">]</mml:mo></mml:mrow></mml:math></disp-formula>where <italic>s</italic> is the spectral exponent with value ∼ 0.021 nm<sup>−1</sup>. The scattering coefficient of SPM <italic>b<sub>spm</sub></italic> is parameterized as [<xref ref-type="bibr" rid="b31-sensors-10-07561">31</xref>]:
<disp-formula id="FD7">
<label>(7)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi>b</mml:mi>
<mml:mi mathvariant="italic">spm</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>=</mml:mo>
<mml:msub>
<mml:mi>b</mml:mi>
<mml:mi mathvariant="italic">spm</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mn>550</mml:mn>
<mml:mo stretchy="false">)</mml:mo>
<mml:msup>
<mml:mrow>
<mml:mo>(</mml:mo>
<mml:mrow>
<mml:mfrac>
<mml:mn>550</mml:mn>
<mml:mi>λ</mml:mi></mml:mfrac></mml:mrow>
<mml:mo>)</mml:mo></mml:mrow>
<mml:mi>y</mml:mi></mml:msup></mml:mrow></mml:math></disp-formula>where <italic>y</italic> is the spectral shape parameter ∼ 1.7. The backscattering fraction of SPM is estimated from the ”San Diego harbor” scattering phase function of Petzold [<xref ref-type="bibr" rid="b32-sensors-10-07561">32</xref>], <italic>i.e.</italic>, <italic>b<sub>b</sub></italic> = 0.0182 × <italic>b</italic>.</p></sec>
<sec>
<label>2.</label>
<title>Estimating the gradient of radiometric observation</title>
<p>Observed remote sensing reflectance can be approximated as being the sum of the model best-fit <italic>Rs<sub>m</sub></italic>(λ) and its deviations from the observed one ε(λ):
<disp-formula id="FD8">
<label>(8)</label>
<mml:math display="block">
<mml:mrow>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>=</mml:mo>
<mml:msub>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mi>m</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo>
<mml:mo>+</mml:mo>
<mml:mi>ɛ</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:math></disp-formula>The term <italic>Rs<sub>m</sub></italic>(λ) is obtained from fitting the model in (1) to the radiometric observation of ocean color or/and field sensors. The error ε(λ) is a lumped term that includes model goodness-of-fit, measurements and atmospheric noises. For simplicity this term is assumed to be nearly independent the derived IOPs. The derivative of (8), with respect to the derived values, can then be written as:
<disp-formula id="FD9">
<label>(9)</label>
<mml:math display="block">
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac>
<mml:mo>=</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:msub>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mi>m</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac>
<mml:mo>+</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mi>ɛ</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac></mml:mrow></mml:math></disp-formula>By definition of the least square minimization that was used to derive model-best-fit <italic>Rs<sub>m</sub></italic>(λ), we have:
<disp-formula id="FD10">
<label>(10)</label>
<mml:math display="block">
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mi>ɛ</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac>
<mml:mo>≈</mml:mo>
<mml:mn>0</mml:mn></mml:mrow></mml:math></disp-formula><xref ref-type="disp-formula" rid="FD9">Equation (9)</xref> can then be reduced to:
<disp-formula id="FD11">
<label>(11)</label>
<mml:math display="block">
<mml:mrow>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac>
<mml:mo>≈</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:msub>
<mml:mi mathvariant="italic">Rs</mml:mi>
<mml:mi>m</mml:mi></mml:msub>
<mml:mo stretchy="false">(</mml:mo>
<mml:mi>λ</mml:mi>
<mml:mo stretchy="false">)</mml:mo></mml:mrow>
<mml:mrow>
<mml:mo>Δ</mml:mo>
<mml:mtext>iop</mml:mtext></mml:mrow></mml:mfrac></mml:mrow></mml:math></disp-formula>The simplification in (11) implies that the gradient of measured remote sensing reflectance can be approximated by the gradient of the model in (1) which can easily be computed.</p></sec>
<sec>
<label>3.</label>
<title>Driving the standard deviation from the plausible range</title>
<p>Salama and Stein [<xref ref-type="bibr" rid="b9-sensors-10-07561">9</xref>] has developed a method to estimate the standard deviation of a log-normally distributed population from its plausible range. Their method starts by generating random values from a normal distribution with zero mean and unity standard deviation, N(0,1). The generated values of N(0,1) satisfy an imposed acceptance-rejection condition. This condition requires that the ratio (13) defines a unique ordered pair of <italic>α</italic>:
<disp-formula id="FD12">
<label>(12)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi>α</mml:mi>
<mml:mi>u</mml:mi></mml:msub>
<mml:mo>=</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>u</mml:mi></mml:msub>
<mml:mo>−</mml:mo>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mrow>
<mml:mi mathvariant="italic">obs</mml:mi></mml:mrow></mml:msub></mml:mrow>
<mml:mi>σ</mml:mi></mml:mfrac></mml:mrow></mml:math></disp-formula>where <bold>iop</bold><italic><sub>u</sub></italic>, <bold>iop</bold><italic><sub>obs</sub></italic> and <italic>σ</italic> are the upper bound of the IOPs; the expectation (derived from model best-fit to observation) and the unknown standard deviation of the population, respectively. All IOPs are log-transformed first. For the lower bound of IOPs, <bold>iop</bold><italic><sub>l</sub></italic>, one can establish the ratio:
<disp-formula id="FD13">
<label>(13)</label>
<mml:math display="block">
<mml:mrow>
<mml:msub>
<mml:mi>r</mml:mi>
<mml:mrow>
<mml:mi>u</mml:mi>
<mml:mo>,</mml:mo>
<mml:mi>l</mml:mi></mml:mrow></mml:msub>
<mml:mo>=</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mi>α</mml:mi>
<mml:mi>u</mml:mi></mml:msub></mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mi>α</mml:mi>
<mml:mi>l</mml:mi></mml:msub></mml:mrow></mml:mfrac>
<mml:mo>=</mml:mo>
<mml:mfrac>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>u</mml:mi></mml:msub>
<mml:mo>−</mml:mo>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>o</mml:mi></mml:msub></mml:mrow>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>l</mml:mi></mml:msub>
<mml:mo>−</mml:mo>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>o</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mrow></mml:math></disp-formula>Three look-up tables (LUTs) are then created from the generated N(0,1) values. These LUTs correspond to the following three scenarios:
<disp-formula id="FD14">
<label>(14)</label>
<mml:math display="block">
<mml:mrow>
<mml:mtable>
<mml:mtr>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>o</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&gt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>u</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&gt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>l</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr>
<mml:mtr>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>o</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&lt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>l</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&lt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>u</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr>
<mml:mtr>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>l</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&lt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>o</mml:mi></mml:msub></mml:mrow></mml:mtd>
<mml:mtd>
<mml:mo>&lt;</mml:mo></mml:mtd>
<mml:mtd>
<mml:mrow>
<mml:msub>
<mml:mtext>iop</mml:mtext>
<mml:mi>u</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mrow></mml:math></disp-formula>The ratio in (13) is first estimated from the log-transformed IOPs values. Based on the value of this ratio a lookup table is selected and searched to find the best-fit. One of the corresponding pair is then used in (12) to compute the standard deviation of the prior PDF.</p></sec>
<sec>
<label>4.</label>
<title>Added random noise</title>
<p>Random normal fluctuations are assumed to be wavelengths dependent with zero mean and standard deviation calculated from the theoretical PDF, see <xref ref-type="fig" rid="f3-sensors-10-07561">Figure 3</xref>.</p></sec></app></app-group>
<sec sec-type="display-objects">
<title>Figures and Tables</title>
<fig id="f1-sensors-10-07561" position="float">
<label>Figure 1.</label>
<caption>
<p>Empirical PDFs generated from field spectra corresponding to predefined quantiles: 0.05 “doted line”, 0.25 “dashed line”, 0.5 “full line”, 0.75 “plus”, 0.9 “square”, 0.95 “circles” for six wavelengths. The theoretical PDF is illustrate as gray area.</p></caption>
<graphic xlink:href="sensors-10-07561f1.gif"/></fig>
<fig id="f2-sensors-10-07561" position="float">
<label>Figure 2.</label>
<caption>
<p>Known <italic>versus</italic> derived variability corresponding to predefined quantiles on a log-scale of radiometric data. The 1:1 line is also shown.</p></caption>
<graphic xlink:href="sensors-10-07561f2.gif"/></fig>
<fig id="f3-sensors-10-07561" position="float">
<label>Figure 3.</label>
<caption>
<p>Relative values of fluctuations added to the aerospace mean for six wavelengths.</p></caption>
<graphic xlink:href="sensors-10-07561f3.gif"/></fig>
<fig id="f4-sensors-10-07561" position="float">
<label>Figure 4.</label>
<caption>
<p>RMS-RE values in estimated <italic>σ</italic> as function of wavelength. The values of <italic>σ</italic> were derived from fluctuated mean and two field spectra corresponding to 0.05 and 0.95 quantiles.</p></caption>
<graphic xlink:href="sensors-10-07561f4.gif"/></fig>
<fig id="f5-sensors-10-07561" position="float">
<label>Figure 5.</label>
<caption>
<p><bold>(a)</bold> Remote sensing reflectance of MERIS full resolution (FR) band 6 centered at 620 nm; <bold>(b)</bold> derived standard deviation of the reduced resolution (RR) MERIS image using the FR pixels; <bold>(c–h)</bold> relative errors of derived (log) standard deviation values of RR-MERIS corresponding to quantiles 0.05, 0.25, 0.5, 0.75, 0.9 and 0.95.</p></caption>
<graphic xlink:href="sensors-10-07561f5.gif"/></fig>
<table-wrap id="t1-sensors-10-07561" position="float">
<label>Table 1.</label>
<caption>
<p>Probability of empirical PDF having the same variability of the theoretical PDF.</p></caption>
<table frame="hsides" rules="groups">
<thead>
<tr>
<th align="left" valign="bottom"/>
<th colspan="6" align="center" valign="bottom">Quantile values
<hr/></th></tr>
<tr>
<th align="left" valign="bottom">band nm/IOPs</th>
<th align="left" valign="bottom">0.05</th>
<th align="left" valign="bottom">0.25</th>
<th align="left" valign="bottom">0.5</th>
<th align="left" valign="bottom">0.75</th>
<th align="left" valign="bottom">0.9</th>
<th align="left" valign="bottom">0.95</th></tr></thead>
<tbody>
<tr>
<td align="left" valign="middle">440</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.26</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.31</td>
<td align="left" valign="middle">0</td></tr>
<tr>
<td align="left" valign="middle">495</td>
<td align="left" valign="middle">0.59</td>
<td align="left" valign="middle">0.19</td>
<td align="left" valign="middle">0.17</td>
<td align="left" valign="middle">0.2</td>
<td align="left" valign="middle">0.11</td>
<td align="left" valign="middle">0.13</td></tr>
<tr>
<td align="left" valign="middle">550</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.01</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.03</td>
<td align="left" valign="middle">0.06</td>
<td align="left" valign="middle">0.57</td></tr>
<tr>
<td colspan="7" align="left" valign="middle">
<hr/></td></tr>
<tr>
<td align="left" valign="middle"><italic>a<sub>phy</sub></italic>(440)</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.09</td>
<td align="left" valign="middle">0.17</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.18</td></tr>
<tr>
<td align="left" valign="middle"><italic>a<sub>dg</sub></italic>(440)</td>
<td align="left" valign="middle">0</td>
<td align="left" valign="middle">0.93</td>
<td align="left" valign="middle">0.09</td>
<td align="left" valign="middle">0.06</td>
<td align="left" valign="middle">0.37</td>
<td align="left" valign="middle">0.58</td></tr>
<tr>
<td align="left" valign="middle"><italic>b<sub>spm</sub></italic>(550)</td>
<td align="left" valign="middle">0.33</td>
<td align="left" valign="middle">0.21</td>
<td align="left" valign="middle">0.34</td>
<td align="left" valign="middle">0.51</td>
<td align="left" valign="middle">0.05</td>
<td align="left" valign="middle">0.3</td></tr></tbody></table></table-wrap>
<table-wrap id="t2-sensors-10-07561" position="float">
<label>Table 2.</label>
<caption>
<p>Relative errors (%) in derived log <italic>σ</italic> values of reflectance estimated from different quantile values. Minus values are underestimated. RMS-RE is the root-mean of squared relative error for all bands.</p></caption>
<table frame="hsides" rules="groups">
<thead>
<tr>
<th align="left" valign="bottom"/>
<th colspan="6" align="center" valign="bottom">Quantile values
<hr/></th></tr>
<tr>
<th align="left" valign="bottom">band nm</th>
<th align="left" valign="bottom">0.05</th>
<th align="left" valign="bottom">0.25</th>
<th align="left" valign="bottom">0.5</th>
<th align="left" valign="bottom">0.75</th>
<th align="left" valign="bottom">0.9</th>
<th align="left" valign="bottom">0.95</th></tr></thead>
<tbody>
<tr>
<td align="left" valign="middle">400</td>
<td align="left" valign="middle">9.08</td>
<td align="left" valign="middle">6.24</td>
<td align="left" valign="middle">10.39</td>
<td align="left" valign="middle">0.77</td>
<td align="left" valign="middle">−13.12</td>
<td align="left" valign="middle">−1.29</td></tr>
<tr>
<td align="left" valign="middle">440</td>
<td align="left" valign="middle">9.78</td>
<td align="left" valign="middle">1.67</td>
<td align="left" valign="middle">6.71</td>
<td align="left" valign="middle">−1.65</td>
<td align="left" valign="middle">−9.29</td>
<td align="left" valign="middle">−1.16</td></tr>
<tr>
<td align="left" valign="middle">495</td>
<td align="left" valign="middle">7.29</td>
<td align="left" valign="middle">−3.91</td>
<td align="left" valign="middle">0.45</td>
<td align="left" valign="middle">−7.32</td>
<td align="left" valign="middle">−9.34</td>
<td align="left" valign="middle">−5.74</td></tr>
<tr>
<td align="left" valign="middle">550</td>
<td align="left" valign="middle">15.35</td>
<td align="left" valign="middle">4.57</td>
<td align="left" valign="middle">8</td>
<td align="left" valign="middle">−1.52</td>
<td align="left" valign="middle">−3.06</td>
<td align="left" valign="middle">−1.53</td></tr>
<tr>
<td align="left" valign="middle">675</td>
<td align="left" valign="middle">10.05</td>
<td align="left" valign="middle">14.81</td>
<td align="left" valign="middle">16.11</td>
<td align="left" valign="middle">6.4</td>
<td align="left" valign="middle">0.61</td>
<td align="left" valign="middle">−0.4</td></tr>
<tr>
<td align="left" valign="middle">695</td>
<td align="left" valign="middle">13.77</td>
<td align="left" valign="middle">20.7</td>
<td align="left" valign="middle">20.99</td>
<td align="left" valign="middle">11.12</td>
<td align="left" valign="middle">3.84</td>
<td align="left" valign="middle">2.32</td></tr>
<tr>
<td colspan="7" align="left" valign="middle">
<hr/></td></tr>
<tr>
<td align="left" valign="middle">RMS-RE</td>
<td align="left" valign="middle">12.5</td>
<td align="left" valign="middle">14.6</td>
<td align="left" valign="middle">14.8</td>
<td align="left" valign="middle">7.6</td>
<td align="left" valign="middle">5.7</td>
<td align="left" valign="middle">2.7</td></tr></tbody></table></table-wrap></sec></back></article>
