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Molbank 2018, 2018(1), M988; doi:10.3390/M988

Cis,exo-1,2,3,4,4a,13b-hexahydro-1,4-methano-5-isopropoxy-9H-tribenzo[b,f]azepine

Department of Chemistry, Life Sciences and Environmental Sustainability (SCVSA), University of Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy
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Received: 20 February 2018 / Revised: 9 March 2018 / Accepted: 10 March 2018 / Published: 12 March 2018
(This article belongs to the Special Issue Molecules from Catalytic Processes)
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Abstract

The title compound—cis,exo-1,2,3,4,4a,13b-hexahydro-1,4-methano-5-isopropoxy-9H-tribenzo[b,f]azepine—was synthesized in 83% isolated yield by a palladium-catalyzed one-pot strategy from 1-iodo-2-isopropoxybenzene and ortho-bromoaniline. The azepine derivative was fully characterized (FT-IR, MS, 1H and 13C-NMR, elemental analysis) and all proton and carbon signals have been completely assigned by 2D NMR experiments. View Full-Text
Keywords: palladium; norbornene; benzo[b,f]azepine; C-C and C-N couplings; multicomponent; one-pot reaction palladium; norbornene; benzo[b,f]azepine; C-C and C-N couplings; multicomponent; one-pot reaction
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Casnati, A.; Motti, E.; Ca’, N.D. Cis,exo-1,2,3,4,4a,13b-hexahydro-1,4-methano-5-isopropoxy-9H-tribenzo[b,f]azepine. Molbank 2018, 2018, M988.

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