Abstract1,2,3,4-Tetra-O-acetyl-β-d-mannuronic acid was synthesized in three steps from commercial d-mannose in 21% yield. Regioselective 6-O-tritylation followed by per-acetylation and 6-OTr removal using HBr/AcOH gave the required primary alcohol substrate, which was then oxidised to the target compound using TEMPO/BAIB. None of the synthetic steps required column chromatography and the product was fully characterized by 1H-NMR, 13C-NMR, 2D NMR, MS and IR. View Full-Text
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Beswick, L.; Miller, G.J. 1,2,3,4-Tetra-O-Acetyl-β-d-Mannuronic Acid. Molbank 2017, 2017, M947.
Beswick L, Miller GJ. 1,2,3,4-Tetra-O-Acetyl-β-d-Mannuronic Acid. Molbank. 2017; 2017(3):M947.Chicago/Turabian Style
Beswick, Laura; Miller, Gavin J. 2017. "1,2,3,4-Tetra-O-Acetyl-β-d-Mannuronic Acid." Molbank 2017, no. 3: M947.
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