Next Article in Journal
4-({4-[(2E)-3-(2,5-Dimethoxyphenyl)prop-2-enoyl]phenyl}amino)-4-oxobutanoic Acid
Previous Article in Journal
5,9,11-Trihydroxy-2,2-dimethyl-3-(2-methylbut-3-en-2-yl)pyrano[2,3-a]xanthen-12(2H)-one from the Stem Bark of Calophyllum tetrapterum Miq.
Article Menu

Export Article

Open AccessShort Note
Molbank 2017, 2017(2), M937; doi:10.3390/M937

Triphenylphosphine-(N,N-dimethyldithiocarbamato)-gold(I) Methanol Solvate

Département de chimie, Université de Montréal, Montréal QC H3C 3J7, Canada; nicolas.belanger.desmarais@umontreal.ca
*
Author to whom correspondence should be addressed.
Received: 1 March 2017 / Revised: 20 March 2017 / Accepted: 23 March 2017 / Published: 30 March 2017
(This article belongs to the Section Structure Determination)
View Full-Text   |   Download PDF [1314 KB, uploaded 1 April 2017]   |  

Abstract

Abstract: A gold(I) complex with a triphenylphosphine and a monodentate N,N-dimethyldithiocarbamate ligand was synthesized and characterized by Raman spectroscopy and single crystal X-ray diffraction. DFT calculations (Gaussian 09, PBE1PBE/Lanl2dz) were undertaken for a single complex in the gas phase. The DFT-optimized structure and calculated Raman spectrum are in good agreement with the crystal structure and the experimental spectrum. Assignments of the Raman peaks are based on these DFT calculations. Frontier molecular orbitals were calculated and their nature is discussed. View Full-Text
Keywords: Au(I) dithiocarbamate and phosphine complex; Raman spectroscopy; single crystal X-ray diffraction; DFT calculations Au(I) dithiocarbamate and phosphine complex; Raman spectroscopy; single crystal X-ray diffraction; DFT calculations
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Supplementary materials

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Bélanger-Desmarais, N.; Reber, C. Triphenylphosphine-(N,N-dimethyldithiocarbamato)-gold(I) Methanol Solvate. Molbank 2017, 2017, M937.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Molbank EISSN 1422-8599 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top