Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin

doi:10.3390/M656

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Molbank 2010, 2010(1), M656; doi:10.3390/M656

Short Note

Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin

Cynthia Pruitt Tidwell ¹^,* , L. Dalila Fondren ¹ and David E. Nikles ²

¹ Department of Biology, Chemistry and Mathematics, University of Montevallo, UM Station 6480, Montevallo, Alabama, USA ² Department of Chemistry, University of Alabama, UA Box 870336, Tuscaloosa, Alabama, USA

* Author to whom correspondence should be addressed.

Received: 18 December 2009 / Accepted: 22 January 2010 / Published: 29 January 2010

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Abstract: Manganese complex of 5,10,15,20-tetra(N-ethyl-3-carbazolyl) porphyrin was synthesized and characterized by electronic absorption spectrophotometry and cyclic voltammetry. The spectral data were in agreement with the proposed structure. The manganese complex exhibited a shift in the Soret band in comparison to the non-metallated porphyrin and the extinction coefficient for the Soret band was on the order of 10⁵ cm^-1M^-1. Trends observed in the oxidation and reduction potentials were consistent with the nature of the porphyrin. That is, the electron donating group in 5,10,15,20-tetra(N-ethyl-3-carbazolyl) porphyrin enhances oxidation and inhibits reduction.

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Cite This Article

MDPI and ACS Style

Pruitt Tidwell, C.; Fondren, L.D.; Nikles, D.E. Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin. Molbank 2010, 2010, M656.

AMA Style

Pruitt Tidwell C., Fondren L.D., Nikles D.E. Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin. Molbank. 2010; 2010(1):M656.

Chicago/Turabian Style

Pruitt Tidwell, Cynthia; Fondren, L. Dalila; Nikles, David E. 2010. "Manganese 5,10,15,20-Tetra(N-ethyl-3-carbazolyl) Porphyrin." Molbank 2010, no. 1: M656.

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