Synthesis of Bis (1-Methyl-2-octynyl) Ether

doi:10.3390/M612

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Molbank 2009, 2009(3), M612; doi:10.3390/M612

Short Note

Synthesis of Bis (1-Methyl-2-octynyl) Ether

David Díaz Díaz * and Víctor S. Martín

Instituto Universitario de Bio-Orgánica “Antonio González”, Universidad de La Laguna, Avda, Astrofísico Francisco Sánchez, 2, 38206 La Laguna, Tenerife, Spain

* Author to whom correspondence should be addressed.

Received: 18 July 2009 / Accepted: 4 August 2009 / Published: 5 August 2009

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Abstract: The synthesis of bis (1-methyl-2-octynyl) ether using two secondary alcohols under Nicholas reaction conditions is reported. The reaction is possible due to a catalytic participation of the Lewis acid when the nucleophilic alcohol is protected as a THPO-ether.

Keywords: Nicholas reaction; cobalt; alkyne complexes

Supplementary Files

Supplementary File 1:
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3D structure generated by CORINA by Molecular Networks.
Supplementary File 2:
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M612-2.mol 3D structure (MOL, 2 KB) Display in MOL Viewer
3D structure generated by CORINA by Molecular Networks.

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Cite This Article

MDPI and ACS Style

Díaz Díaz, D.; Martín, V.S. Synthesis of Bis (1-Methyl-2-octynyl) Ether. Molbank 2009, 2009, M612.

AMA Style

Díaz Díaz D., Martín V.S. Synthesis of Bis (1-Methyl-2-octynyl) Ether. Molbank. 2009; 2009(3):M612.

Chicago/Turabian Style

Díaz Díaz, David; Martín, Víctor S. 2009. "Synthesis of Bis (1-Methyl-2-octynyl) Ether." Molbank 2009, no. 3: M612.

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