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Int. J. Mol. Sci. 2007, 8(6), 505-512; doi:10.3390/i8060505
Article

Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones

1,* , 2, 2 and 3
Received: 14 December 2006; in revised form: 23 April 2007 / Accepted: 25 May 2007 / Published: 6 June 2007
(This article belongs to the Special Issue Ionic Liquids)
Abstract: The selective oxidation of alcohols with molecular oxygen was efficientlycompleted in high conversion and selectivity using copper-bisisoquinoline-based catalystsunder mild reaction condition. The effects of various parameters such as reactiontemperature, reaction time, oxidant, ligands, etc, were studied. Solvent effect has been aswell studied in ionic liquids [bmim]PF6, [omim]BF4 and [hmim]BF4, comparing totraditional volatile organic solvent. The use of ionic liquids was found to enhance thecatalytic properties of the catalysts used.
Keywords: selective oxidation of alcohols; copper-bisisoquinoline-based catalysts; ionic liquids. selective oxidation of alcohols; copper-bisisoquinoline-based catalysts; ionic liquids.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Shen, H.-Y.; Ying, L.-Y.; Jiang, H.-L.; Judeh, Z.M.A. Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones. Int. J. Mol. Sci. 2007, 8, 505-512.

AMA Style

Shen H-Y, Ying L-Y, Jiang H-L, Judeh ZMA. Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones. International Journal of Molecular Sciences. 2007; 8(6):505-512.

Chicago/Turabian Style

Shen, Hao-Yu; Ying, Li-Yan; Jiang, Hai-Liang; Judeh, Zaher M.A. 2007. "Efficient Copper-bisisoquinoline-based Catalysts for Selective Aerobic Oxidation of Alcohols to Aldehydes and Ketones." Int. J. Mol. Sci. 8, no. 6: 505-512.


Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert