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Int. J. Mol. Sci. 2007, 8(1), 29-41; doi:10.3390/i8010029
Article

Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2

1, 1,*  and 2,*
1 Gannan Normal University, Ganzhou, 341000, JiangXi, People’s Republic of China 2 Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, People’s Republic of China
* Authors to whom correspondence should be addressed.
Received: 28 November 2006 / Revised: 3 January 2007 / Accepted: 16 January 2007 / Published: 30 January 2007
(This article belongs to the Section Molecular Recognition)
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Abstract

Two supramolecular coordination polymers, [HgI2(L1)·0.5H2O] (1) and[HgI2(L2)·0.4CH3OH] (2), have been prepared by ligands L1 (L1 = bis[4-(4-pyridylmethyleneamino)phenyl] ether) and L2 (L2 = N,N′-bis(3-pyridylmethyl)-diphthalicdiimide) with HgI2, respectively. 1 formed an interestingly infinite cross-linked doublehelical structure, whereas 2 formed the one-dimensional zigzag chains, which are parallelwith each other.
Keywords: Hg(II) complex; coordination polymers; bis[4-(4-pyridylmethyleneamino)- phenyl] ether; N; N′-bis(3-pyridylmethyl)-diphthalic diimide Hg(II) complex; coordination polymers; bis[4-(4-pyridylmethyleneamino)- phenyl] ether; N; N′-bis(3-pyridylmethyl)-diphthalic diimide
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Li, X.; Fan, X.; Zeng, Q. Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2. Int. J. Mol. Sci. 2007, 8, 29-41.

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