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Int. J. Mol. Sci. 2007, 8(1), 29-41; doi:10.3390/i8010029
Article

Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2

1, 1,*  and 2,*
1 Gannan Normal University, Ganzhou, 341000, JiangXi, People’s Republic of China 2 Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, People’s Republic of China
* Authors to whom correspondence should be addressed.
Received: 28 November 2006 / Revised: 3 January 2007 / Accepted: 16 January 2007 / Published: 30 January 2007
(This article belongs to the Section Molecular Recognition)
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Abstract

Two supramolecular coordination polymers, [HgI2(L1)·0.5H2O] (1) and[HgI2(L2)·0.4CH3OH] (2), have been prepared by ligands L1 (L1 = bis[4-(4-pyridylmethyleneamino)phenyl] ether) and L2 (L2 = N,N′-bis(3-pyridylmethyl)-diphthalicdiimide) with HgI2, respectively. 1 formed an interestingly infinite cross-linked doublehelical structure, whereas 2 formed the one-dimensional zigzag chains, which are parallelwith each other.
Keywords: Hg(II) complex; coordination polymers; bis[4-(4-pyridylmethyleneamino)- phenyl] ether; N; N′-bis(3-pyridylmethyl)-diphthalic diimide Hg(II) complex; coordination polymers; bis[4-(4-pyridylmethyleneamino)- phenyl] ether; N; N′-bis(3-pyridylmethyl)-diphthalic diimide
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Li, X.; Fan, X.; Zeng, Q. Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2. Int. J. Mol. Sci. 2007, 8, 29-41.

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