Int. J. Mol. Sci. 2004, 5(4), 174-185; doi:10.3390/i5040174
Article

Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes

1, 2, 2 and 2,* email
Received: 15 December 2003; Accepted: 11 March 2004 / Published: 1 April 2004
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Cambridge Structural Database (CSD) was screened in order to find intramolecular C−H···π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C−H···π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.
Keywords: C−H···π interactions; transition metal complexes; chelate ring; porphyrin; axial ligands
PDF Full-text Download PDF Full-Text [339 KB, uploaded 19 June 2014 00:03 CEST]

Export to BibTeX |
EndNote


MDPI and ACS Style

Bogdanović, G.A.; Medaković, V.; Milčić, M.K.; Zarić, S.D. Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes. Int. J. Mol. Sci. 2004, 5, 174-185.

AMA Style

Bogdanović GA, Medaković V, Milčić MK, Zarić SD. Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes. International Journal of Molecular Sciences. 2004; 5(4):174-185.

Chicago/Turabian Style

Bogdanović, Goran A.; Medaković, Vesna; Milčić, Miloš K.; Zarić, Snežana D. 2004. "Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes." Int. J. Mol. Sci. 5, no. 4: 174-185.

Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert