Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes
AbstractCambridge Structural Database (CSD) was screened in order to find intramolecular C−H···π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C−H···π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.
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Bogdanović, G.A.; Medaković, V.; Milčić, M.K.; Zarić, S.D. Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes. Int. J. Mol. Sci. 2004, 5, 174-185.
Bogdanović GA, Medaković V, Milčić MK, Zarić SD. Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes. International Journal of Molecular Sciences. 2004; 5(4):174-185.Chicago/Turabian Style
Bogdanović, Goran A.; Medaković, Vesna; Milčić, Miloš K.; Zarić, Snežana D. 2004. "Intramolecular C−H···π Interactions in Metal-Porphyrin Complexes." Int. J. Mol. Sci. 5, no. 4: 174-185.