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Int. J. Mol. Sci. 2011, 12(8), 5352-5372; doi:10.3390/ijms12085352
Review
Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years?
1
Stranski Lab for Physical and Theoretical Chemistry, Berlin Institute of Technology, 135-17 June Street, Berlin 10623, Germany
2
Department of Chemical and Biomolecular Engineering, North Carolina State University, 911 Partners Way, Raleigh, NC 27695, USA
* Author to whom correspondence should be addressed.
Received: 6 July 2011; in revised form: 9 August 2011 / Accepted: 11 August 2011 / Published: 22 August 2011
(This article belongs to the Special Issue Liquid Crystals 2011)
The original version is still available [921 KB, uploaded 22 August 2011 11:15 CEST]
Abstract: Liquid crystals have attracted enormous interest because of the variety of their phases and richness of their application. The interplay of general physical symmetries and specific molecular features generates a myriad of different phenomena. A surprising behavior of liquid crystals is the reentrancy of phases as temperature, pressure, or concentration are varied. Here, we review the main experimental facts and the different theoretical scenarios that have guided the understanding of bulk reentrant nematics. Recently, some computer simulations of a system confined to nanoscopic scales have found new dynamical features of the reentrant nematic phase. We discuss this prediction in relation with the available experimental evidence on reentrant nematics and with the dynamics of liquids in strongly confined environments.
Keywords: reentrant phase; nematic; dynamics; diffusion
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MDPI and ACS Style
Mazza, M.G.; Schoen, M. Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years? Int. J. Mol. Sci. 2011, 12, 5352-5372.
AMA StyleMazza MG, Schoen M. Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years? International Journal of Molecular Sciences. 2011; 12(8):5352-5372.
Chicago/Turabian StyleMazza, Marco G.; Schoen, Martin. 2011. "Structure and Dynamics of Reentrant Nematics: Any Open Questions after Almost 40 Years?" Int. J. Mol. Sci. 12, no. 8: 5352-5372.
Int. J. Mol. Sci.
EISSN 1422-0067
Published by MDPI AG, Basel, Switzerland
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