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Int. J. Mol. Sci. 2011, 12(3), 1464-1473; doi:10.3390/ijms12031464

pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates

1,* , 1,2
2,* , 1
1 School of Chemistry, Monash University, Wellington road, Clayton Victoria 3800, Australia 2 Department of Organic Chemistry, North Maharashtra University, Jalgaon 425 001, India
* Authors to whom correspondence should be addressed.
Received: 27 January 2011 / Revised: 17 February 2011 / Accepted: 22 February 2011 / Published: 24 February 2011
(This article belongs to the Special Issue Molecular Self-Assembly)
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Self-assembled nanostructures of zwitterionic octaphosphanatoporphyrin 1, of either nanoparticles or nanorods, depending on small changes in the pH, is demonstrated based on the J-aggregates. Porphyrin 1 self-assembled into nanosphere aggregates with a diameter of about 70–80 nm in the pH range 5–7, and nanorod aggregates were observed at pH 8.5. Hydrogen bonding, p-p stacking and hydrophilic interactions play important roles in the formation of this nanostructure morphology. Nanostructures were characterized by UV/Vis absorbance, fluorescence, atomic force microscopy (AFM) and transmission electron microscopy (TEM). This interesting pH dependent self-assembly phenomenon could provide a basis for development of novel biomaterials.
Keywords: molecular self-assembly; porphyrin; aggregation; AFM; TEM molecular self-assembly; porphyrin; aggregation; AFM; TEM
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Bhosale, S.V.; Kalyankar, M.B.; Nalage, S.V.; Lalander, C.H.; Bhosale, S.V.; Langford, S.J.; Oliver, R.F. pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates. Int. J. Mol. Sci. 2011, 12, 1464-1473.

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