Int. J. Mol. Sci. 2011, 12(3), 1464-1473; doi:10.3390/ijms12031464
Article

pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates

Received: 27 January 2011; in revised form: 17 February 2011 / Accepted: 22 February 2011 / Published: 24 February 2011
(This article belongs to the Special Issue Molecular Self-Assembly)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Self-assembled nanostructures of zwitterionic octaphosphanatoporphyrin 1, of either nanoparticles or nanorods, depending on small changes in the pH, is demonstrated based on the J-aggregates. Porphyrin 1 self-assembled into nanosphere aggregates with a diameter of about 70–80 nm in the pH range 5–7, and nanorod aggregates were observed at pH 8.5. Hydrogen bonding, p-p stacking and hydrophilic interactions play important roles in the formation of this nanostructure morphology. Nanostructures were characterized by UV/Vis absorbance, fluorescence, atomic force microscopy (AFM) and transmission electron microscopy (TEM). This interesting pH dependent self-assembly phenomenon could provide a basis for development of novel biomaterials.
Keywords: molecular self-assembly; porphyrin; aggregation; AFM; TEM
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MDPI and ACS Style

Bhosale, S.V.; Kalyankar, M.B.; Nalage, S.V.; Lalander, C.H.; Bhosale, S.V.; Langford, S.J.; Oliver, R.F. pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates. Int. J. Mol. Sci. 2011, 12, 1464-1473.

AMA Style

Bhosale SV, Kalyankar MB, Nalage SV, Lalander CH, Bhosale SV, Langford SJ, Oliver RF. pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates. International Journal of Molecular Sciences. 2011; 12(3):1464-1473.

Chicago/Turabian Style

Bhosale, Sheshanath V.; Kalyankar, Mohan B.; Nalage, Santosh V.; Lalander, Cecilia H.; Bhosale, Sidhanath V.; Langford, Steven J.; Oliver, Ruth F. 2011. "pH Dependent Molecular Self-Assembly of Octaphosphonate Porphyrin of Nanoscale Dimensions: Nanosphere and Nanorod Aggregates." Int. J. Mol. Sci. 12, no. 3: 1464-1473.

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