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Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System
WPI Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
Department of Physics, Yeshiva University, 500 West 185th Street, New York, NY 10033, USA
Department of Physics, Brooklyn College of the City University of New York, Brooklyn, NY 11210, USA
Center for Polymer Studies and Department of Physics, Boston University, Boston, MA 02215, USA
* Author to whom correspondence should be addressed.
Received: 16 November 2010; in revised form: 13 December 2010 / Accepted: 13 December 2010 / Published: 16 December 2010
Abstract: We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.
Keywords: glass transition; polyamorphism; liquid-liquid phase transition
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Cite This Article
MDPI and ACS Style
Xu, L.; Buldyrev, S.V.; Giovambattista, N.; Stanley, H.E. Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System. Int. J. Mol. Sci. 2010, 11, 5184-5200.
Xu L, Buldyrev SV, Giovambattista N, Stanley HE. Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System. International Journal of Molecular Sciences. 2010; 11(12):5184-5200.
Xu, Limei; Buldyrev, Sergey V.; Giovambattista, Nicolas; Stanley, H. Eugene. 2010. "Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System." Int. J. Mol. Sci. 11, no. 12: 5184-5200.