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Int. J. Mol. Sci. 2009, 10(9), 3931-3936; doi:10.3390/ijms10093931
Communication

Molecule Non-Radiative Coupling to a Metallic Nanosphere: An Optical Theorem Treatment

Received: 10 July 2009; in revised form: 1 September 2009 / Accepted: 4 September 2009 / Published: 8 September 2009
(This article belongs to the Special Issue Single Molecules)
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Abstract: The non-radiative coupling of a molecule to a metallic spherical particle is approximated by a sum involving particle quasistatic polarizabilities. We demonstrate that energy transfer from molecule to particle satisfies the optical theorem if size effects corrections are properly introduced into the quasistatic polarizabilities. We hope that this simplified model gives valuable information on the coupling mechanism between molecule and metallic nanostructures available for, e.g., surface enhanced spectroscopy signal analysis.
Keywords: surface enhanced spectroscopy; energy transfer; optical theorem; plasmon modes surface enhanced spectroscopy; energy transfer; optical theorem; plasmon modes
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Des Francs, G.C. Molecule Non-Radiative Coupling to a Metallic Nanosphere: An Optical Theorem Treatment. Int. J. Mol. Sci. 2009, 10, 3931-3936.

AMA Style

Des Francs GC. Molecule Non-Radiative Coupling to a Metallic Nanosphere: An Optical Theorem Treatment. International Journal of Molecular Sciences. 2009; 10(9):3931-3936.

Chicago/Turabian Style

Des Francs, Gérard C. 2009. "Molecule Non-Radiative Coupling to a Metallic Nanosphere: An Optical Theorem Treatment." Int. J. Mol. Sci. 10, no. 9: 3931-3936.



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