Molecules 2004, 9(9), 746-756; doi:10.3390/90900746

N-Salicylideneamine Derivatives with TEMPO Substituents

, ,  and * email
Received: 25 April 2004; Accepted: 21 May 2004 / Published: 31 August 2004
(This article belongs to the Special Issue Ferromagnetic Organic Radicals)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Three N-salicylideneamine derivatives bearing TEMPO (2,2,6,6-tetra- methyl-1-piperidinyloxy) substituents were prepared in order to study their structure and property relationships and to investigate the possibilities of the existence of heat and/or light responsive magnetic properties. Curie-Weiss behavior with weak ferromagnetic intermolecular spin-spin interactions was observed in one of the radicals, while antiferromagnetic interactions were predominant for the other radicals and the structure-property relationships were investigated for the radical compounds from their crystal structures obtained by X-ray analyses. Preliminary results of the examination of their responses towards light and heat are also described.
Keywords: Salicylideneamine; salicylideneaniline; TEMPO; magnetic property; crystal structure
PDF Full-text Download PDF Full-Text [263 KB, uploaded 18 June 2014 19:26 CEST]

Export to BibTeX |

MDPI and ACS Style

Hata, M.; Akutsu, H.; Yamada, J.-I.; Nakatsuji, S. N-Salicylideneamine Derivatives with TEMPO Substituents. Molecules 2004, 9, 746-756.

AMA Style

Hata M, Akutsu H, Yamada J-I, Nakatsuji S. N-Salicylideneamine Derivatives with TEMPO Substituents. Molecules. 2004; 9(9):746-756.

Chicago/Turabian Style

Hata, Masayuki; Akutsu, Hiroki; Yamada, Jun-ichi; Nakatsuji, Shin’ichi. 2004. "N-Salicylideneamine Derivatives with TEMPO Substituents." Molecules 9, no. 9: 746-756.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert