Chemical Manganese Dioxide (CMD): lts Application to the Oxidative Iodination of Benzene, Halobenzenes and Some Deactivated Arenes †

doi:10.3390/90700595

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Molecules 2004, 9(7), 595-601; doi:10.3390/90700595

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Chemical Manganese Dioxide (CMD): lts Application to the Oxidative Iodination of Benzene, Halobenzenes and Some Deactivated Arenes †

Piotr Lulinski, Barbara Krassowska-Swiebocka and Lech Skulski *

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University of Warsaw, 1 Banacha Street, PL 02-097 Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 23 April 2004 / Accepted: 8 May 2004 / Published: 30 June 2004

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Abstract: After comparing our previous and newer results for numerous oxidativearomatic iodination experiments using various brands of active MnO₂ as the oxidants,we recommend the use of a Chemical Manganese Dioxide (Aldrich CMD; 90 %MnO₂) as the oxidant of choice, since it is satisfactorily pure and chemically active, andis notably less costly than other options.

Keywords: Iodinated arenas; arenas; oxidative aromatic iodination; chemical manganese dioxide as oxidant.

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MDPI and ACS Style

Lulinski, P.; Krassowska-Swiebocka, B.; Skulski, L. Chemical Manganese Dioxide (CMD): lts Application to the Oxidative Iodination of Benzene, Halobenzenes and Some Deactivated Arenes †. Molecules 2004, 9, 595-601.

AMA Style

Lulinski P., Krassowska-Swiebocka B., Skulski L. Chemical Manganese Dioxide (CMD): lts Application to the Oxidative Iodination of Benzene, Halobenzenes and Some Deactivated Arenes †. Molecules. 2004; 9(7):595-601.

Chicago/Turabian Style

Lulinski, Piotr; Krassowska-Swiebocka, Barbara; Skulski, Lech. 2004. "Chemical Manganese Dioxide (CMD): lts Application to the Oxidative Iodination of Benzene, Halobenzenes and Some Deactivated Arenes †." Molecules 9, no. 7: 595-601.

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