Molecules 2004, 9(5), 287-299; doi:10.3390/90500287
Article

Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone

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Received: 2 February 2004; Accepted: 8 March 2004 / Published: 30 April 2004
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The commercially available monoterpene carvone has been efficiently convertedinto the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of somebiologically active compounds. The sequence used for this transformation involves as keyfeatures an intramolecular Diels-Alder reaction of a 5-vinyl-1,3-cyclohexadiene and acyclopropane ring opening.
Keywords: Carvone; Diels-Alder reaction; cyclopropane cleavage; 5-vinyl-1; 3- cyclohexadiene; samarium diiodide; bicyclo[3.2.1]octane; tricyclo[3.2.1.02.7]octane
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MDPI and ACS Style

Abad, A.; Agulló, C.; Cuñat, A.C.; De Alfonso, I.; Navarro, I.; Vera, N. Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone. Molecules 2004, 9, 287-299.

AMA Style

Abad A, Agulló C, Cuñat AC, De Alfonso I, Navarro I, Vera N. Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone. Molecules. 2004; 9(5):287-299.

Chicago/Turabian Style

Abad, Antonio; Agulló, Consuelo; Cuñat, Ana C.; De Alfonso, Ignacio; Navarro, Ismael; Vera, Noelia. 2004. "Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone." Molecules 9, no. 5: 287-299.

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