Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

doi:10.3390/90100022

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Molecules 2004, 9(1), 22-28; doi:10.3390/90100022

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Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers

S. Servi * and C. Topaloglu

Department of Chemistry, Firat University, Faculty of Science and Arts, 23169, Elazig, Turkey

* Author to whom correspondence should be addressed.

Received: 25 September 2003; in revised form: 9 January 2004 / Accepted: 19 January 2004 / Published: 31 January 2004

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Abstract: Heteroaryl substituted allyl and homoallyl alcohols were synthesised with two different method. Synthesis of bis-allyl ethers and homoallyl ethers were carried out via reaction of allyl bromide with allyl alcohols and homoallyl alcohols, respectively. [2.3]-Wittig Rearrangement reactions of heteroaryl substituted bis-allyl ethers were investigated using GC/MS techniques. In these reactions two unexpected products were isolated in high yield.

Keywords: Nozaki-Hiyama reaction; Organochromium reagents; Hetero- aromatic aldehydes

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MDPI and ACS Style

Servi, S.; Topaloglu, C. Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers. Molecules 2004, 9, 22-28.

AMA Style

Servi S., Topaloglu C. Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers. Molecules. 2004; 9(1):22-28.

Chicago/Turabian Style

Servi, S.; Topaloglu, C. 2004. "Addition of Organochromium Reagents to Heteroaryl Aldehydes. Synthesis of Heteroaryl Substituted bis-Allyl Ethers and Homoallyl Ethers." Molecules 9, no. 1: 22-28.

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