Molecules 2003, 8(5), 411-417; doi:10.3390/80500411
Article

Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4

1,* email, 1, 2,*, 2 and 3
Received: 9 February 2003; in revised form: 3 April 2003 / Accepted: 6 April 2003 / Published: 31 May 2003
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The binuclear zinc (II) complex Zn2[(n-Bu)2NCSS]4 has been prepared, and its crystal and molecular structure have been determined by x-ray diffraction. The crystal is monoclinic, space group C2/c, with a=23.329(3)Å, b=17.090(2)Å, c=16.115(2)Å, α =90°, β=127.560(10)°, γ=90°, z=4, V=5039.1(11)Å3, F(000)=2016, R=0.0450, and Rw=0.1192. The crystal structure shows that two S-N-S atom chains, belonging to the different dibutyldithiocarbamate ligands, bridge two zinc (II) ions. Each zinc (II) ion coordinates to four S atoms. The coordination geometry around the zinc (II) is a tetrahedron, however, the coordination sphere of two zinc ions in the dimer is best described as a distorted octagon. The X-ray photoelectron spectra, IR and UV data have been used to study the structure and spectra properties of the complex.
Keywords: Synthesis; zinc complex; dithiocarbamate; crystal structure
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MDPI and ACS Style

Zhang, W.; Zhong, Y.; Tan, M.; Tang, N.; Yu, K. Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4. Molecules 2003, 8, 411-417.

AMA Style

Zhang W, Zhong Y, Tan M, Tang N, Yu K. Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4. Molecules. 2003; 8(5):411-417.

Chicago/Turabian Style

Zhang, Weiguang; Zhong, Yun; Tan, Minyu; Tang, Ning; Yu, Kaibei. 2003. "Synthesis and Structure of bis(Dibutyldithiocarbamate)zinc(II): Zn2[(n-Bu)2NCSS]4." Molecules 8, no. 5: 411-417.

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