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Molecules 2002, 7(2), 189-199; doi:10.3390/70200189
Article

Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

*  and
College of Chemistry, Isfahan University of Technology, Isfahan, I.R. Iran
* Author to whom correspondence should be addressed.
Received: 12 November 2001 / Revised: 5 February 2002 / Accepted: 5 February 2002 / Published: 28 February 2002
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Abstract

The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N3, (Ar = p-NO2-C6H4-, p-Br-C6H4-, p-Cl-C6H4-, p-C6H5-, p-CH3-C6H4-, 2,4-dimethyl-C6H3-, 2,4,6-trimethyl-C6H2-, p-CH3O-C6H4- and Z = p-CH3-C6H4-SO2-, 2,4,6-trimethyl-C6H2-SO2-,CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined.
Keywords: Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity
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Dabbagh, H.A.; Karimzadeh, R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules 2002, 7, 189-199.

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