Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

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Molecules 2002, 7(2), 189-199; doi:10.3390/70200189

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Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

Hossein A. Dabbagh* and Reza Karimzadeh

College of Chemistry, Isfahan University of Technology, Isfahan, I.R. Iran

* Author to whom correspondence should be addressed.

Received: 12 November 2001; in revised form: 5 February 2002 / Accepted: 5 February 2002 / Published: 28 February 2002

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Abstract: The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N3, (Ar = p-NO₂-C₆H₄-, p-Br-C₆H₄-, p-Cl-C₆H₄-, p-C₆H₅-, p-CH₃-C₆H₄-, 2,4-dimethyl-C₆H₃-, 2,4,6-trimethyl-C₆H₂-, p-CH₃O-C₆H₄- and Z = p-CH₃-C₆H₄-SO₂-, 2,4,6-trimethyl-C₆H₂-SO₂-,CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined.

Keywords: Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity

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MDPI and ACS Style

Dabbagh, H.A.; Karimzadeh, R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules 2002, 7, 189-199.

AMA Style

Dabbagh HA, Karimzadeh R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules. 2002; 7(2):189-199.

Chicago/Turabian Style

Dabbagh, Hossein A.; Karimzadeh, Reza. 2002. "Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors." Molecules 7, no. 2: 189-199.

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