Molecules 2002, 7(2), 189-199; doi:10.3390/70200189
Article

Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors

College of Chemistry, Isfahan University of Technology, Isfahan, I.R. Iran
* Author to whom correspondence should be addressed.
Received: 12 November 2001; in revised form: 5 February 2002 / Accepted: 5 February 2002 / Published: 28 February 2002
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Abstract: The thermal decomposition of imidoyl azides (ArO-C=N-Z)-N3, (Ar = p-NO2-C6H4-, p-Br-C6H4-, p-Cl-C6H4-, p-C6H5-, p-CH3-C6H4-, 2,4-dimethyl-C6H3-, 2,4,6-trimethyl-C6H2-, p-CH3O-C6H4- and Z = p-CH3-C6H4-SO2-, 2,4,6-trimethyl-C6H2-SO2-,CN) in the solid phase and in anisole has been studied in detail. The sensitivity of nitrenes and nitrene precursors (imidoyl azides) towards substitution changes in the aryloxy (ArO) and Z moieties is examined.
Keywords: Imidoyl azides; Imidoylnitrenes; Reactivity; Selectivity

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MDPI and ACS Style

Dabbagh, H.A.; Karimzadeh, R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules 2002, 7, 189-199.

AMA Style

Dabbagh HA, Karimzadeh R. Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors. Molecules. 2002; 7(2):189-199.

Chicago/Turabian Style

Dabbagh, Hossein A.; Karimzadeh, Reza. 2002. "Functionalization of Phenyl Rings by Imidoylnitrenes. 3 The Effects of Resonance, Steric, and Inductive Properties on the Reactivity or Selectivity of Nitrenes and the Stability of their Precursors." Molecules 7, no. 2: 189-199.

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