Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant

doi:10.3390/71100810

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Molecules 2002, 7(11), 810-812; doi:10.3390/71100810

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Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant

Pawel Kazmierczak and Lech Skulski*

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, PL 02-097, 1 Banacha Street, Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 15 October 2002; in revised form: 21 October 2002 / Accepted: 21 October 2002 / Published: 30 November 2002

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Abstract: Easy and effective preparations of the nearly pure [bis(trifluoroacetoxy)-iodo]arenes, ArI(OCOCF)₃, from some iodoarenes, ArI, are reported, using an anhydrous sodium percarbonate/(CF₃CO)₂O/CH₂Cl₂ system. The colorless, freshly prepared ArI(OCOCF₃)₂ thus obtained were 98-99% pure (by iodometry).

Keywords: [Bis(trifluoroacetoxy)iodo]arenes from iodoarenes; sodium percarbonate as oxidant

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MDPI and ACS Style

Kazmierczak, P.; Skulski, L. Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant. Molecules 2002, 7, 810-812.

AMA Style

Kazmierczak P, Skulski L. Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant. Molecules. 2002; 7(11):810-812.

Chicago/Turabian Style

Kazmierczak, Pawel; Skulski, Lech. 2002. "Easy Preparation of [Bis(trifluoroacetoxy)iodo]arenes from Iodoarenes, with Sodium Percarbonate as the Oxidant." Molecules 7, no. 11: 810-812.

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