Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant

doi:10.3390/61100881

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Molecules 2001, 6(11), 881-891; doi:10.3390/61100881

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Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant

Pawel Kazmierczak, Lech Skulski * and Lukasz Kraszkiewicz

Chair and Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University, Banacha 1, PL 02-097 Warsaw, Poland

* Author to whom correspondence should be addressed.

Received: 27 September 2001; in revised form: 11 October 2001 / Accepted: 12 October 2001 / Published: 31 October 2001

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Abstract: - Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)₂, or iodylarenes, ArIO₂, from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids.

Keywords: (Diacetoxyiodo)arenes; iodylarenes; iodoarenes; sodium periodate as oxidant

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MDPI and ACS Style

Kazmierczak, P.; Skulski, L.; Kraszkiewicz, L. Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant. Molecules 2001, 6, 881-891.

AMA Style

Kazmierczak P., Skulski L., Kraszkiewicz L. Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant. Molecules. 2001; 6(11):881-891.

Chicago/Turabian Style

Kazmierczak, Pawel; Skulski, Lech; Kraszkiewicz, Lukasz. 2001. "Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant." Molecules 6, no. 11: 881-891.

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