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Molecules 2001, 6(1), 61-66; doi:10.3390/60100061
Article

Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

1, 1, 2, 1 and 2,*
Received: 6 December 2000 / Revised: 7 January 2001 / Accepted: 8 January 2001 / Published: 16 January 2001
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Abstract

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH -form) vinyl silanes are converted into epoxysilanes.
Keywords: Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent
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Domann, S.; Sourkouni-Argirusi, G.; Merayo, N.; Schönberger, A.; Kirschning, A. Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents. Molecules 2001, 6, 61-66.

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