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Molecules 2001, 6(1), 61-66; doi:10.3390/60100061

Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

1, 1, 2, 1 and 2,*
1 Institut für Organische Chemie der Technischen Universität Clausthal, Leibnizstraße 6, D-38678 Clausthal-Zellerfeld, Germany 2 Institut für Organische Chemie, Universität Hannover, Schneiderberg 1B, D-30167 Hannover, Germany
* Author to whom correspondence should be addressed.
Received: 6 December 2000 / Revised: 7 January 2001 / Accepted: 8 January 2001 / Published: 16 January 2001
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Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH -form) vinyl silanes are converted into epoxysilanes.
Keywords: Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent
This is an open access article distributed under the Creative Commons Attribution License (CC BY) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Domann, S.; Sourkouni-Argirusi, G.; Merayo, N.; Schönberger, A.; Kirschning, A. Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents. Molecules 2001, 6, 61-66.

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