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Molecules 2001, 6(1), 61-66; doi:10.3390/60100061

Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

1, 1, 2, 1 and 2,*
1 Institut für Organische Chemie der Technischen Universität Clausthal, Leibnizstraße 6, D-38678 Clausthal-Zellerfeld, Germany 2 Institut für Organische Chemie, Universität Hannover, Schneiderberg 1B, D-30167 Hannover, Germany
* Author to whom correspondence should be addressed.
Received: 6 December 2000 / Revised: 7 January 2001 / Accepted: 8 January 2001 / Published: 16 January 2001
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Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH -form) vinyl silanes are converted into epoxysilanes.
Keywords: Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent Cohalogenation; allylsilane; vinylsilane; polymer-supported reagent
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Domann, S.; Sourkouni-Argirusi, G.; Merayo, N.; Schönberger, A.; Kirschning, A. Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents. Molecules 2001, 6, 61-66.

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