Molecules 2000, 5(2), 132-152; doi:10.3390/50200132
Article

1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes

* email, ,  and
Received: 25 January 2000; Accepted: 14 February 2000 / Published: 18 February 2000
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The 1,3-dipolar cycloaddition reaction of N-benzyl-C-(2-furyl)nitrones with electron-rich alkenes gives preferentially trans-substituted 3,5-disubstituted isoxazolidines (endo approach). These experimental results are in good qualitative agreement with the predicted ones by semiempirical (AM1 and PM3) and ab initio (HF/3-21G) methods.
Keywords: Nitrones; isoxazolidines; pyrrolidines; theoretical calculations; cycloaddition
PDF Full-text Download PDF Full-Text [369 KB, uploaded 18 June 2014 19:25 CEST]

Export to BibTeX |
EndNote


MDPI and ACS Style

Merino, P.; Anoro, S.; Merchan, F.L.; Tejero, T. 1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes. Molecules 2000, 5, 132-152.

AMA Style

Merino P, Anoro S, Merchan FL, Tejero T. 1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes. Molecules. 2000; 5(2):132-152.

Chicago/Turabian Style

Merino, Pedro; Anoro, Sonia; Merchan, Francisco L.; Tejero, Tomas. 2000. "1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes." Molecules 5, no. 2: 132-152.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert