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Molecules 2017, 22(5), 833; doi:10.3390/molecules22050833

Electrophilic Trifluoromethylselenolation of Boronic Acids

1
Institute of Chemistry and Biochemistry (ICBMS-UMR CNRS 5246), Université de Lyon, Université Lyon 1, CNRS, F-69622 Lyon, France
2
CERMEP—In Vivo Imaging, Groupement Hospitalier Est, F-69677 Lyon, France
*
Author to whom correspondence should be addressed.
Academic Editor: Derek J. McPhee
Received: 1 May 2017 / Revised: 13 May 2017 / Accepted: 15 May 2017 / Published: 19 May 2017
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Abstract

Trifluoromethylselenylated compounds are emergent compounds with interesting physicochemical properties that still suffer from a lack of efficient synthetic methods. We recently developed an efficient one-pot strategy to generate in situ CF3SeCl and use it in various reactions. Herein, we continue our study of the reactivity scope of this preformed reagent. Cross-coupling reactions with aromatic and heteroaromatic boronic acids have been investigated. The expected products have been obtained, using a stoichiometric amount of copper, with moderate yields. View Full-Text
Keywords: trifluoromethylselenolation; boronic acids; trifluoromethylselenyl chloride; fluorine; selenium trifluoromethylselenolation; boronic acids; trifluoromethylselenyl chloride; fluorine; selenium
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Ghiazza, C.; Tlili, A.; Billard, T. Electrophilic Trifluoromethylselenolation of Boronic Acids. Molecules 2017, 22, 833.

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