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Erratum published on 26 May 2017, see Molecules 2017, 22(6), 877.

Open AccessArticle
Molecules 2017, 22(4), 640; doi:10.3390/molecules22040640

Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants

1,2
and
1,*
1
State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, China
2
Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, College of Life Sciences, Tarim University, Alar, Xinjiang 843300, China
*
Author to whom correspondence should be addressed.
Academic Editor: Wim Dehaen
Received: 22 March 2017 / Revised: 11 April 2017 / Accepted: 12 April 2017 / Published: 16 April 2017
(This article belongs to the Section Organic Synthesis)
View Full-Text   |   Download PDF [1955 KB, uploaded 31 May 2017]   |  

Abstract

4-Sulfoalkanoic acids are a class of important dianionic-headed surfactants. Various 4-sulfoalkanoic acids with straight C8, C10, C12, C14, C16, and C18 chains were synthesized expeditiously through the radical addition of methyl 2-((ethoxycarbonothioyl)thio)acetate to linear terminal olefins and subsequent oxidation with peroxyformic acid. This is a useful and convenient strategy for the synthesis of dianionic-headed surfactants with a carboxylic acid and sulfonic acid functionalities in the head group region. View Full-Text
Keywords: alkanoic acid; double head; oxidation; radical reaction; surfactant; xanthate alkanoic acid; double head; oxidation; radical reaction; surfactant; xanthate
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Jiang, J.; Xu, J. Expeditious Synthesis of Dianionic-Headed 4-Sulfoalkanoic Acid Surfactants. Molecules 2017, 22, 640.

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