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Molecules 2017, 22(12), 2278; https://doi.org/10.3390/molecules22122278

A Water Cluster Conduit in Crystal

School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, China
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Received: 25 October 2017 / Revised: 13 December 2017 / Accepted: 14 December 2017 / Published: 20 December 2017
(This article belongs to the Section Inorganic Chemistry)
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Abstract

The crystal structure of compound (1), [CuCl(phen)(H2NCH2COO)]∙4H2O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H2O)14]n, resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H2O)14]n planes are bridged by Cl atoms in [CuCl(phen) (H2NCH2COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit. View Full-Text
Keywords: glycine; water cluster; nanometer sized; crystal; hydrogen-bond glycine; water cluster; nanometer sized; crystal; hydrogen-bond
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Jian, F.; Liu, E.; Xu, J. A Water Cluster Conduit in Crystal. Molecules 2017, 22, 2278.

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