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Molecules 2017, 22(12), 2044; doi:10.3390/molecules22122044

Recyclable Magnetic Titania Nanocomposite from Ilmenite with Enhanced Photocatalytic Activity

1
Department of Chemistry and Chemical Engineering, Shaoxing Univeristy, Shaoxing 312000, China
2
Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China
*
Author to whom correspondence should be addressed.
Received: 19 October 2017 / Revised: 9 November 2017 / Accepted: 20 November 2017 / Published: 23 November 2017
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Abstract

Using ilmenite as a raw material, iron was converted into Fe3O4 magnetic fluid, which further was combined with titanium filtrate by a solvothermal method. Finally Fe3O4/TiO2 nanocomposites with the uniform size of 100–200 nm were prepared. This approach uses rich, inexpensive ilmenite as a titanium and iron source, which effectively reduces the production cost. The crystal structure, chemical properties and morphologies of the products were characterized by SEM, TEM, XRD, FTIR, BET, UV-Vis, XPS and VSM. The novel photocatalyst composed of face-centered cubic Fe3O4 and body-centered tetragonal anatase–TiO2 exhibits a spherical shape with porous structures, superparamagnetic behavior and strong absorption in the visible light range. Using the degradation reaction of Rhodamine B (RhB) to evaluate the photocatalytic performance, the results suggest that Fe3O4/TiO2 nanocomposites exhibit excellent photocatalytic activities and stability under visible light and solar light. Moreover, the magnetic titania nanocomposites displayed good magnetic response and were recoverable over several cycles. Based on the trapping experiments, the main active species in the photocatalytic reaction were confirmed and the possible photocatalytic mechanism of RhB with magnetic titania was proposed. The enhanced photocatalytic activity and stability, combined with excellent magnetic recoverability, make the prepared nanocomposite a potential candidate in wastewater purification. View Full-Text
Keywords: ilmenite; titania; nanocomposite; photocatalysis; magnetic recyclability ilmenite; titania; nanocomposite; photocatalysis; magnetic recyclability
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Hong, T.; Mao, J.; Tao, F.; Lan, M. Recyclable Magnetic Titania Nanocomposite from Ilmenite with Enhanced Photocatalytic Activity. Molecules 2017, 22, 2044.

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