Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

doi:10.3390/jan97p4

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Molecules 1997, 2(1), 11-16; doi:10.3390/jan97p4

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Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

Ping Cao, Zheng-Yu Long and Qing-Yun Chen *

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China

* Author to whom correspondence should be addressed.

Received: 5 December 1996 / Accepted: 15 January 1997 / Published: 29 January 1997

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Abstract: Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu₂NO) and the free radical inhibitor (hydroquinone) suppressed the reaction. A photoinduced electron-transfer mechanism is proposed.

Keywords: Photochemistry; pentafluoroiodobenzene; alkene; single electron-transfer; free radical inhibitor

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MDPI and ACS Style

Cao, P.; Long, Z.-Y.; Chen, Q.-Y. Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes. Molecules 1997, 2, 11-16.

AMA Style

Cao P., Long Z.-Y., Chen Q.-Y. Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes. Molecules. 1997; 2(1):11-16.

Chicago/Turabian Style

Cao, Ping; Long, Zheng-Yu; Chen, Qing-Yun. 1997. "Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes." Molecules 2, no. 1: 11-16.

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