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Molecules 2014, 19(10), 15783-15785; doi:10.3390/molecules191015783

Special Issue: Intramolecular Hydrogen Bonding

Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, FL 32611-7200, USA
Received: 26 September 2014 / Revised: 27 September 2014 / Accepted: 27 September 2014 / Published: 29 September 2014
(This article belongs to the Special Issue Intramolecular Hydrogen Bonding)
View Full-Text   |   Download PDF [610 KB, uploaded 29 September 2014]

Abstract

Intramolecular hydrogen bonds play critical structure- and function-serving roles in biological and synthetic molecular systems. This special issue, through eight contributions, showcases the prominence of these non-covalent interactions within several scientific disciplines, and in various structural contexts and environments. Reported, for example, are the consequences of intramolecular hydrogen bonds on the structures of molecules that show biological activity, for biological mechanisms, and for the conformational switching of functional synthetic molecules. Also showcased in the contributions are the state-of-the-art experimental and theoretical methods available for the characterization of intramolecular hydrogen bonds, which critically report on their strengths, geometries, and spectroscopic signatures in the gas, solid, and solution phases. View Full-Text
Keywords: conformation; cooperativity; H-bonding; host-guest chemistry; non-covalent interactions; resonance-assisted hydrogen bonds; self-assembly; supramolecular chemistry; tautomerism; three-center hydrogen bonds conformation; cooperativity; H-bonding; host-guest chemistry; non-covalent interactions; resonance-assisted hydrogen bonds; self-assembly; supramolecular chemistry; tautomerism; three-center hydrogen bonds
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Castellano, R.K. Special Issue: Intramolecular Hydrogen Bonding. Molecules 2014, 19, 15783-15785.

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