Next Article in Journal
Previous Article in Journal
Molecules 2012, 17(3), 3501-3509; doi:10.3390/molecules17033501
Article

Synthesis and Structural Determination of Novel 5-Arylidene-3-N(2-alkyloxyaryl)-2-thioxothiazolidin-4-ones

1, 1,* , 2
 and 1
Received: 5 January 2012; in revised form: 26 February 2012 / Accepted: 1 March 2012 / Published: 19 March 2012
Download PDF [241 KB, uploaded 18 June 2014]
Abstract: As part of our project devoted to the synthesis of heterocycles including thiazole rings, some new 5-arylidene-2-thioxo-3-N-arylthiazolidin-4-ones were synthesized by Knoevenagel condensation. An interesting feature of these compounds is that their chirality is induced by that of their 3-N-(2-alkyloxyaryl)-2-thioxothiazolidin-4-one precursors, which in turn is due to the presence of a C2 axis of chirality. These new compounds were characterized by spectroscopic methods (IR, 1H-NMR, 13C-NMR). The structure of compound (Z)-(2g) was further determined by X-ray diffraction.
Keywords: N-arylthiazolidin-4-one; (Z)-5-arylidene-3-N-arylthiazolidin-4-one; chirality; IR; 1H-NMR; 13C-NMR; X-ray diffraction; nonlinear optical properties; solar cells N-arylthiazolidin-4-one; (Z)-5-arylidene-3-N-arylthiazolidin-4-one; chirality; IR; 1H-NMR; 13C-NMR; X-ray diffraction; nonlinear optical properties; solar cells
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Toubal, K.; Djafri, A.; Chouaih, A.; Talbi, A. Synthesis and Structural Determination of Novel 5-Arylidene-3-N(2-alkyloxyaryl)-2-thioxothiazolidin-4-ones. Molecules 2012, 17, 3501-3509.

AMA Style

Toubal K, Djafri A, Chouaih A, Talbi A. Synthesis and Structural Determination of Novel 5-Arylidene-3-N(2-alkyloxyaryl)-2-thioxothiazolidin-4-ones. Molecules. 2012; 17(3):3501-3509.

Chicago/Turabian Style

Toubal, Khaled; Djafri, Ayada; Chouaih, Abdelkader; Talbi, Abdou. 2012. "Synthesis and Structural Determination of Novel 5-Arylidene-3-N(2-alkyloxyaryl)-2-thioxothiazolidin-4-ones." Molecules 17, no. 3: 3501-3509.



Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert