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Molecules 2011, 16(11), 9067-9076; https://doi.org/10.3390/molecules16119067

Linear Polystyrene-Stabilized PdO Nanoparticle-Catalyzed Mizoroki-Heck Reactions in Water

1
Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
2
Nanomaterials and Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
*
Authors to whom correspondence should be addressed.
Received: 19 September 2011 / Revised: 22 October 2011 / Accepted: 26 October 2011 / Published: 27 October 2011
(This article belongs to the Special Issue Reactions in Water)
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Abstract

Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)2 in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
Keywords: polystyrene; PdO nanoparticles; Mizoroki-Heck reaction; water polystyrene; PdO nanoparticles; Mizoroki-Heck reaction; water
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Ohtaka, A.; Yamaguchi, T.; Teratani, T.; Shimomura, O.; Nomura, R. Linear Polystyrene-Stabilized PdO Nanoparticle-Catalyzed Mizoroki-Heck Reactions in Water. Molecules 2011, 16, 9067-9076.

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